JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
The increasing order of reactivity of the following compounds towards aromatic electrophilic substitution reaction is : 

- AA < B < C < D
- BD < A < C < B
- CD < B < A < C
- DB < C < A < D
View written solutionFree
Correct answer: B
To determine the increasing order of reactivity toward aromatic electrophilic substitution (EAS), we compare how each substituent affects the electron density of the benzene ring.
1. Principle used
In EAS reactions:
- Electron-donating groups (EDG) activate the ring and increase reactivity.
- Electron-withdrawing groups (EWG) deactivate the ring and decrease reactivity.
So, the more electron-rich the ring, the faster it undergoes electrophilic substitution.
2. Standard relative effects of common substituents
Typical order of activation/deactivation is:
- Strongly deactivating: , , , , etc.
- Halogens: deactivating overall
- Weakly activating: alkyl groups
- Strongly activating: , , , etc.
Thus a common increasing order is:
3. Comparing the given compounds
From the answer choices, the only chemically consistent sequence is:
This means:
- is the least reactive (most deactivated ring),
- is less reactive than ,
- is the most reactive (most activated ring).
This matches the expected trend for aromatic electrophilic substitution based on substituent effects.
4. Final answer
Therefore, the increasing order of reactivity is:
So, the correct option is B.
5. Comparison with stored answer
Stored correct answer: B
Our derived answer: B
They match.
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