- A
- B
- C

- DCCl , NaOH
View written solutionFree
Correct answer: A
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Identify the product asked:
Salicylaldehyde is o-hydroxybenzaldehyde.
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Recall the named reaction for preparing salicylaldehyde from phenol:
Phenol on treatment with chloroform and aqueous sodium hydroxide undergoes the Reimer–Tiemann reaction.
In this reaction, the formyl group is introduced mainly at the ortho position of phenol, giving salicylaldehyde.
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Check the options:
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A:
This is chloroform + sodium hydroxide, i.e. Reimer–Tiemann reaction. It gives salicylaldehyde. So correct.
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B:
This is related to the Kolbe–Schmitt reaction, which gives salicylic acid after acidification, not salicylaldehyde. So incorrect.
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D:
With and base, phenol gives salicylic acid (after hydrolysis), not salicylaldehyde. So incorrect.
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Conclusion:
The reagent needed to synthesize salicylaldehyde from phenol is:
Hence, Option A is correct.
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