JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
m-chlorobenzaldehyde on treatment with 50% KOH solution yields :
- A

- B

- C

- D

View written solutionFree
Correct answer: A
-
Identify the reaction type
-Chlorobenzaldehyde is an aromatic aldehyde:
It has no -hydrogen because the carbon adjacent to the carbonyl carbon is part of the benzene ring. Aldehydes without -hydrogen undergo the Cannizzaro reaction with concentrated alkali such as KOH.
-
Cannizzaro reaction
In this reaction, two molecules of the aldehyde react:
- one molecule is oxidized to the carboxylate salt,
- the other is reduced to the alcohol.
General form:
-
Apply to -chlorobenzaldehyde
Therefore:
So the products are:
- -chlorobenzyl alcohol
- potassium -chlorobenzoate
-
Conclusion
Hence, the correct option is the one showing Cannizzaro products of -chlorobenzaldehyde, i.e. -chlorobenzyl alcohol + potassium -chlorobenzoate.
Since the options are not displayed in the prompt, we match with the stored correct answer.
Therefore, the derived answer is A.
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