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Aldehydes Ketones and Carboxylic Acids question

2024 · 30 Jan · Shift 1 · Q5
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  5. /2024 · 30 Jan · Shift 1 · Q5

Aldehydes Ketones and Carboxylic Acids question

2024 · 30 Jan · Shift 1 · Q5

JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
JEE Main 2024 (Online) 30th January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 44 English This reduction reaction is known as:
  1. A
    Wolff-Kishner reduction
  2. B
    Etard reduction
  3. C
    Stephen reduction
  4. D
    Rosenmund reduction
View written solutionFree

Correct answer: D

  1. Identify the reaction name from the options

    The named reductions given are:

    • Wolff–Kishner reduction: converts aldehydes/ketones to hydrocarbons.
    • Etard reaction: oxidation of a benzylic methyl group to an aldehyde.
    • Stephen reduction: reduction of nitriles to aldehydes.
    • Rosenmund reduction: reduction of acid chlorides to aldehydes using hydrogen over poisoned palladium catalyst.
  2. Match the reaction type

    The reaction referred to here is the reduction of an acid chloride to an aldehyde:

    RCOCl→poisoned PdH2RCHO\mathrm{RCOCl \xrightarrow[poisoned\ Pd]{H_2} RCHO}RCOClH2​poisoned Pd​RCHO

    This is specifically called the Rosenmund reduction.

  3. Check the options

    • A: Wolff-Kishner reduction →\rightarrow→ incorrect
    • B: Etard reduction →\rightarrow→ incorrect
    • C: Stephen reduction →\rightarrow→ incorrect
    • D: Rosenmund reduction →\rightarrow→ correct
  4. Final answer

    The reduction reaction is Rosenmund reduction.

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