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Aldehydes Ketones and Carboxylic Acids question

2024 · 31 Jan · Shift 2 · Q14
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Aldehydes Ketones and Carboxylic Acids question

2024 · 31 Jan · Shift 2 · Q14

JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
Identify the name reaction. JEE Main 2024 (Online) 31st January Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 51 English
  1. A
    Stephen Reaction
  2. B
    Etard Reaction
  3. C
    Gatterman - Koch Reaction
  4. D
    Rosenmund Reduction
View written solutionFree

Correct answer: C

  1. Identify the transformation shown by the named reaction

    The reaction referred to in this question is the formylation of an aromatic ring using carbon monoxide and hydrogen chloride in the presence of a catalyst such as anhydrous AlCl3/CuCl\mathrm{AlCl_3/CuCl}AlCl3​/CuCl.

    This introduces a −CHO-CHO−CHO (aldehyde) group onto an aromatic ring:

    Ar−H→AlCl3/CuClCO+HClAr−CHO\mathrm{Ar-H \xrightarrow[AlCl_3/CuCl]{CO + HCl} Ar-CHO}Ar−HCO+HClAlCl3​/CuCl​Ar−CHO

  2. Match with the correct name reaction

    This reaction is known as the Gattermann–Koch reaction.

  3. Check the other options

    • A: Stephen Reaction
      Converts nitriles into aldehydes by reduction followed by hydrolysis.
    • B: Etard Reaction
      Oxidation of a methyl group on an aromatic ring to an aldehyde using chromyl chloride.
    • C: Gatterman - Koch Reaction
      Introduces a formyl group into an aromatic ring using CO\mathrm{CO}CO and HCl\mathrm{HCl}HCl. ✅
    • D: Rosenmund Reduction
      Converts acid chlorides into aldehydes using poisoned palladium catalyst.
  4. Conclusion

    The reaction is Gattermann–Koch Reaction.

    Hence, the correct option is:

    C\boxed{\text{C}}C​

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