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Aldehydes Ketones and Carboxylic Acids question

2024 · 30 Jan · Shift 1 · Q20
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Aldehydes Ketones and Carboxylic Acids question

2024 · 30 Jan · Shift 1 · Q20

JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
Structure of 4-Methylpent-2-enal is :
  1. A
    JEE Main 2024 (Online) 30th January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 43 English Option 1
  2. B
    JEE Main 2024 (Online) 30th January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 43 English Option 2
  3. C
    JEE Main 2024 (Online) 30th January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 43 English Option 3
  4. D
    JEE Main 2024 (Online) 30th January Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 43 English Option 4
View written solutionFree

Correct answer: C

  1. Interpret the IUPAC name: 4-Methylpent-2-enal

    Let us break the name into parts:

    • pent ⇒\Rightarrow⇒ main chain has 5 carbons
    • enal ⇒\Rightarrow⇒ aldehyde group (−CHO)(-CHO)(−CHO) is present, and it is carbon 1
    • 2-en ⇒\Rightarrow⇒ double bond is between carbon 2 and carbon 3
    • 4-methyl ⇒\Rightarrow⇒ a methyl group is attached to carbon 4
  2. Write the parent chain numbering

    Since aldehyde carbon is always carbon 1:

    C1−C2=C3−C4−C5\text{C1} - \text{C2} = \text{C3} - \text{C4} - \text{C5}C1−C2=C3−C4−C5

    with C1=−CHO\text{C1} = -CHOC1=−CHO

  3. Add the substituent at carbon 4

    A methyl group at carbon 4 gives:

    CHO−CH=CH−CH(CH3)−CH3\text{CHO} - \text{CH}=\text{CH} - \text{CH}(CH_3) - \text{CH}_3CHO−CH=CH−CH(CH3​)−CH3​

  4. Write the condensed structure clearly

    The structure is:

    OHC−CH=CH−CH(CH3)−CH3OHC-CH=CH-CH(CH_3)-CH_3OHC−CH=CH−CH(CH3​)−CH3​

    or equivalently,

    CH3−CH(CH3)−CH=CH−CHOCH_3-CH(CH_3)-CH=CH-CHOCH3​−CH(CH3​)−CH=CH−CHO

  5. Match with the options

    The correct option must represent:

    CH3−CH(CH3)−CH=CH−CHOCH_3-CH(CH_3)-CH=CH-CHOCH3​−CH(CH3​)−CH=CH−CHO

    This corresponds to Option C.

  6. Comparison with stored answer

    Stored correct answer = C

    Derived answer = C

    Hence, they agree.

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