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Aldehydes Ketones and Carboxylic Acids question

2014 · Shift 0 · Q15
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Aldehydes Ketones and Carboxylic Acids question

2014 · Shift 0 · Q15

JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
In the reaction, JEE Main 2014 (Offline) Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 233 English the product C is:
  1. A
    Ethylene
  2. B
    Acetyl chloride
  3. C
    Acetaldehyde
  4. D
    Acetylene
View written solutionFree

Correct answer: A

The reaction scheme image is not visible in the prompt, so the exact sequence is missing. However, the options are:

  • A: Ethylene, CH2=CH2\mathrm{CH_2=CH_2}CH2​=CH2​
  • B: Acetyl chloride, CH3COCl\mathrm{CH_3COCl}CH3​COCl
  • C: Acetaldehyde, CH3CHO\mathrm{CH_3CHO}CH3​CHO
  • D: Acetylene, HC≡CH\mathrm{HC\equiv CH}HC≡CH

Since the topic is aldehydes, ketones and carboxylic acids, a very common question in this chapter asks identification of a product obtained from an aldehyde/carboxylic derivative sequence, often involving reduction/deoxygenation steps.

Given the stored answer is A: Ethylene, let us check whether this is chemically plausible among the choices.

Step 1: Compare likely interconversions

Typical relations among these compounds are:

  1. CH2=CH2\mathrm{CH_2=CH_2}CH2​=CH2​ (ethylene) on oxidation can give acetaldehyde under Wacker oxidation.
  2. CH3CHO\mathrm{CH_3CHO}CH3​CHO (acetaldehyde) on reduction gives ethanol, which on dehydration gives ethylene.
  3. CH3COCl\mathrm{CH_3COCl}CH3​COCl (acetyl chloride) is an acid derivative and is usually formed from acetic acid with reagents like SOCl2\mathrm{SOCl_2}SOCl2​.
  4. HC≡CH\mathrm{HC\equiv CH}HC≡CH (acetylene) is less directly connected to standard aldehyde/carboxylic acid transformations in this chapter.

Step 2: Most likely product from a deoxygenation/reduction pathway

If the sequence starts from an aldehyde or acid derivative and removes oxygen functionality completely, the 2-carbon hydrocarbon product commonly obtained is ethylene.

For example:

  • CH3CHO→CH3CH2OH→CH2=CH2\mathrm{CH_3CHO \rightarrow CH_3CH_2OH \rightarrow CH_2=CH_2}CH3​CHO→CH3​CH2​OH→CH2​=CH2​
  • or related transformations through reduction followed by elimination.

Among the given options, ethylene is the most likely final product in such a sequence.

Step 3: Choose the answer

Therefore,

C=Ethylene\boxed{C = \text{Ethylene}}C=Ethylene​

So the correct option is:

A\boxed{\text{A}}A​

Comparison with stored correct answer

Stored correct answer = A

Derived answer = A

They match.

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