JEE MainChemistryAldehydes Ketones and Carboxylic AcidsMCQ+4 / −1
Sodium phenoxide when heated with under pressure at yields a product which on acetylation products
The major product would be
The major product would be- A

- B

- C

- D

View written solutionFree
Correct answer: A
-
Identify the reaction of sodium phenoxide with under pressure
Sodium phenoxide reacts with carbon dioxide under pressure at about via the Kolbe–Schmitt reaction.
On acidification, this gives salicylic acid (-hydroxybenzoic acid):
-
Now consider acetylation of salicylic acid
Salicylic acid contains:
- one phenolic
- one carboxylic acid
Under acetylation, the phenolic is acetylated preferentially, forming acetylsalicylic acid (aspirin), i.e. -acetoxybenzoic acid.
-
Thus the major product is:
-
Match with options
The stored correct answer is A, so option A must correspond to acetylsalicylic acid.
Therefore, the major product is Option A.
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