- AStatement 1 is True, Statement 2 is True; Statement 2 is a CORRECT explanation for Statement 1.
- BStatement 1 is True, Statement 2 is True; Statement 2 is a NOT CORRECT explanation for Statement 1.
- CStatement 1 is True, Statement 2 is False.
- DStatement 1 is False, Statement 2 is True.
View written solutionFree
Correct answer: A
Step-by-step Derivations:
Step 1: Analyze Statement 1
Statement 1 says: "There is a natural asymmetry between converting work to heat and converting heat to work."
-
Converting Work to Heat: This process can be 100% efficient. For example, the work done by friction is completely converted into heat, increasing the internal energy of the surfaces. Another example is an electrical resistor, where electrical work is entirely converted into heat (). According to the first law of thermodynamics, . If we do work on an insulated system (), its internal energy increases by . This increased internal energy can be subsequently released as heat. So, work can be completely converted into heat.
-
Converting Heat to Work: This process is performed by a heat engine. A heat engine operates in a cycle, absorbs heat () from a high-temperature reservoir, converts part of it into work (), and must reject the remaining heat () to a low-temperature reservoir. The efficiency of a heat engine is given by . According to the Second Law of Thermodynamics, it is impossible to convert heat completely into work in a cyclic process. This means is always less than 1 (or 100%). For 100% conversion, would equal , which would imply . This is forbidden by the Second Law.
-
Conclusion for Statement 1: Since work can be completely converted to heat, but heat cannot be completely converted to work, there is a clear asymmetry between the two processes. Therefore, Statement 1 is True.
Step 2: Analyze Statement 2
Statement 2 says: "No process is possible in which the sole result is the absorption of heat from a reservoir and its complete conversion into work."
- This is the Kelvin-Planck statement of the Second Law of Thermodynamics. It is one of the fundamental postulates of thermodynamics.
- It essentially states that it is impossible to construct a perpetual motion machine of the second kind - a device that would continuously take heat from a single source (like the ocean) and convert it all into useful work, without any other effect (like rejecting some heat to a colder body).
- As this is a fundamental law of physics, Statement 2 is True.
Step 3: Analyze the relationship between Statement 1 and Statement 2
- Statement 1 describes an observed phenomenon: the asymmetry in energy conversion.
- Statement 2 provides the fundamental physical law that governs this phenomenon.
- The reason for the asymmetry mentioned in Statement 1 is precisely the principle articulated in Statement 2. The conversion of heat to work is restricted (it cannot be 100% complete in a cycle), while the conversion of work to heat is not. Statement 2 is the formal statement of this restriction on converting heat to work.
- Therefore, Statement 2 is the correct explanation for Statement 1.
Step 4: Final Conclusion
Both Statement 1 and Statement 2 are true, and Statement 2 provides the correct scientific explanation for Statement 1. This corresponds to option A.
Final Answer: The correct option is A.
More from Thermodynamics
- The value of log K for a reaction is (Given : kJ mol , J K mol and R = 8.314 J K mol…2007 · MCQ
- Considering ideal gas behavior, the expansion work done (in kJ) when 144 g of water is electrolyzed completely under constant pressure at 300 K is . Use: Universal gas constant (R) = 8.3 J K−1 mol−1; Atomic mass…2025 · Numerical
- Consider the following volume-temperature diagram for the expansion of 5 moles of an ideal monoatomic gas. Considering only work is involved, the total change in enthalpy (in Joule) for the… Includes diagram2024 · Numerical
- One mole of an ideal monoatomic gas undergoes two reversible processes and as shown in the given figure: is an adiabatic process.… Includes diagram2023 · Numerical
- In a one-litre flask, 6 moles of undergoes the reaction . The progress of product formation at two temperatures (in Kelvin), and , is shown in the figure:… Includes diagram2023 · Numerical
- The entropy versus temperature plot for phases and at 1 bar pressure is given. and are entropies of the phases at temperatures and , respectively. The transition… Includes diagram2023 · Numerical
- The entropy versus temperature plot for phases and at 1 bar pressure is given. and are entropies of the phases at temperatures and , respectively. The transition… Includes diagram2023 · Numerical
- is combusted in a fixed volume bomb calorimeter with excess of at and 1 atm into . During the reaction, temperature increases…2022 · Numerical