JEE AdvancedChemistrySolid StateMultiple correct+4 / −2
Atoms of metals , and form face-centred cubic (fcc) unit cell of edge length , body-centred cubic (bcc) unit cell of edge length , and simple cubic unit cell of edge length , respectively. If and , then the correct statement(s) is(are) : [Given: , and are molar masses of metals , and , respectively. , and are atomic radii of metals , and , respectively.]
- APacking efficiency of unit cell of Packing efficiency of unit cell of Packing efficiency of unit cell of
- B
- C
- DDensity of Density of
View written solutionFree
Correct answer: A, B, D
- Use the relation between atomic radius and edge length
For different cubic unit cells:
-
fcc: atoms touch along face diagonal
-
bcc: atoms touch along body diagonal
-
simple cubic: atoms touch along edge
Given:
- Compare packing efficiencies
Standard packing efficiencies are:
- simple cubic:
- bcc:
- fcc:
So,
Hence Option A is correct.
- Compare and
We have
and
Now compare:
Therefore,
Hence Option B is correct.
- Compare and
Using
First,
Next,
Now compare:
So,
Hence Option C is incorrect.
- Compare densities of and
Density formula:
where is number of atoms per unit cell.
- For (fcc):
- For (bcc):
Given:
So,
Now,
Thus,
Since from above , we get
Hence Option D is correct.
- Final answer
Correct options are:
This matches the stored correct answer.
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