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Solid State question

2023 · Shift 2 · Q6
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Solid State question

2023 · Shift 2 · Q6

JEE AdvancedChemistrySolid StateMultiple correct+4 / −2
Atoms of metals x,y\mathrm{x}, \mathrm{y}x,y, and z\mathrm{z}z form face-centred cubic (fcc) unit cell of edge length Lx\mathrm{L}_{\mathrm{x}}Lx​, body-centred cubic (bcc) unit cell of edge length Ly\mathrm{L}_yLy​, and simple cubic unit cell of edge length Lz\mathrm{L}_zLz​, respectively. If rz=32ry;ry=83rx;Mz=32My\mathrm{r}_{\mathrm{z}}=\frac{\sqrt{3}}{2} r_{\mathrm{y}} ; \mathrm{r}_{\mathrm{y}}=\frac{8}{\sqrt{3}} \mathrm{r}_{\mathrm{x}} ; M_{\mathrm{z}}=\frac{3}{2} M_{\mathrm{y}}rz​=23​​ry​;ry​=3​8​rx​;Mz​=23​My​ and Mz=3MxM_{\mathrm{z}}=3 M_{\mathrm{x}}Mz​=3Mx​, then the correct statement(s) is(are) : [Given: Mx,MyM_x, M_yMx​,My​, and MzM_zMz​ are molar masses of metals x,yx, yx,y, and zzz, respectively. rx,ry\mathrm{r}_{\mathrm{x}}, \mathrm{r}_{\mathrm{y}}rx​,ry​, and rz\mathrm{r}_{\mathrm{z}}rz​ are atomic radii of metals x,y\mathrm{x}, \mathrm{y}x,y, and z\mathrm{z}z, respectively.]
  1. A
    Packing efficiency of unit cell of x>x\gtx> Packing efficiency of unit cell of y>y\gty> Packing efficiency of unit cell of zzz
  2. B
    Ly>Lz\mathrm{L}_{\mathrm{y}}\gt \mathrm{L}_{\mathrm{z}}Ly​>Lz​
  3. C
    Lx>Ly\mathrm{L}_{\mathrm{x}}\gt \mathrm{L}_{\mathrm{y}}Lx​>Ly​
  4. D
    Density of x>x\gtx> Density of yyy
View written solutionFree

Correct answer: A, B, D

  1. Use the relation between atomic radius and edge length

For different cubic unit cells:

  • fcc: atoms touch along face diagonal 4rx=2 Lx⇒Lx=22 rx4r_x = \sqrt{2}\,L_x \Rightarrow L_x = 2\sqrt{2}\,r_x4rx​=2​Lx​⇒Lx​=22​rx​

  • bcc: atoms touch along body diagonal 4ry=3 Ly⇒Ly=4ry34r_y = \sqrt{3}\,L_y \Rightarrow L_y = \frac{4r_y}{\sqrt{3}}4ry​=3​Ly​⇒Ly​=3​4ry​​

  • simple cubic: atoms touch along edge Lz=2rzL_z = 2r_zLz​=2rz​

Given: rz=32ry,ry=83rxr_z = \frac{\sqrt{3}}{2}r_y, \qquad r_y = \frac{8}{\sqrt{3}}r_xrz​=23​​ry​,ry​=3​8​rx​


  1. Compare packing efficiencies

Standard packing efficiencies are:

  • simple cubic: 52.4%52.4\%52.4%
  • bcc: 68.0%68.0\%68.0%
  • fcc: 74.0%74.0\%74.0%

So, Packing efficiency of x>Packing efficiency of y>Packing efficiency of z\text{Packing efficiency of }x > \text{Packing efficiency of }y > \text{Packing efficiency of }zPacking efficiency of x>Packing efficiency of y>Packing efficiency of z

Hence Option A is correct.


  1. Compare LyL_yLy​ and LzL_zLz​

We have Lz=2rz=2(32ry)=3 ryL_z = 2r_z = 2\left(\frac{\sqrt{3}}{2}r_y\right) = \sqrt{3}\,r_yLz​=2rz​=2(23​​ry​)=3​ry​

and Ly=4ry3L_y = \frac{4r_y}{\sqrt{3}}Ly​=3​4ry​​

Now compare: LyLz=4ry33ry=43>1\frac{L_y}{L_z} = \frac{\frac{4r_y}{\sqrt{3}}}{\sqrt{3}r_y} = \frac{4}{3} > 1Lz​Ly​​=3​ry​3​4ry​​​=34​>1

Therefore, Ly>LzL_y > L_zLy​>Lz​

Hence Option B is correct.


  1. Compare LxL_xLx​ and LyL_yLy​

Using ry=83rxr_y = \frac{8}{\sqrt{3}}r_xry​=3​8​rx​

First, Lx=22rxL_x = 2\sqrt{2}r_xLx​=22​rx​

Next, Ly=4ry3=43⋅83rx=323rxL_y = \frac{4r_y}{\sqrt{3}} = \frac{4}{\sqrt{3}}\cdot \frac{8}{\sqrt{3}}r_x = \frac{32}{3}r_xLy​=3​4ry​​=3​4​⋅3​8​rx​=332​rx​

Now compare: Lx=22rx≈2.828rxL_x = 2\sqrt{2}r_x \approx 2.828r_xLx​=22​rx​≈2.828rx​ Ly=323rx≈10.667rxL_y = \frac{32}{3}r_x \approx 10.667r_xLy​=332​rx​≈10.667rx​

So, Lx<LyL_x < L_yLx​<Ly​

Hence Option C is incorrect.


  1. Compare densities of xxx and yyy

Density formula: ρ=ZMNAL3\rho = \frac{Z M}{N_A L^3}ρ=NA​L3ZM​

where ZZZ is number of atoms per unit cell.

  • For xxx (fcc): Zx=4Z_x = 4Zx​=4
  • For yyy (bcc): Zy=2Z_y = 2Zy​=2

Given: Mz=3Mx,Mz=32MyM_z = 3M_x, \qquad M_z = \frac{3}{2}M_yMz​=3Mx​,Mz​=23​My​

So, 3Mx=32My⇒My=2Mx3M_x = \frac{3}{2}M_y \Rightarrow M_y = 2M_x3Mx​=23​My​⇒My​=2Mx​

Now, ρx=4MxNALx3,ρy=2MyNALy3=2(2Mx)NALy3=4MxNALy3\rho_x = \frac{4M_x}{N_A L_x^3}, \qquad \rho_y = \frac{2M_y}{N_A L_y^3} = \frac{2(2M_x)}{N_A L_y^3} = \frac{4M_x}{N_A L_y^3}ρx​=NA​Lx3​4Mx​​,ρy​=NA​Ly3​2My​​=NA​Ly3​2(2Mx​)​=NA​Ly3​4Mx​​

Thus, ρxρy=Ly3Lx3\frac{\rho_x}{\rho_y} = \frac{L_y^3}{L_x^3}ρy​ρx​​=Lx3​Ly3​​

Since from above Ly>LxL_y > L_xLy​>Lx​, we get ρx>ρy\rho_x > \rho_yρx​>ρy​

Hence Option D is correct.


  1. Final answer

Correct options are: A, B, D\boxed{A,\ B,\ D}A, B, D​

This matches the stored correct answer.

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