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Solid State question

2021 · Shift 1 · Q3
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Solid State question

2021 · Shift 1 · Q3

JEE AdvancedChemistrySolid StateMCQ+3 / −1
For the given close packed structure of a salt made of cation X and anion Y shown below (ions of only one face are shown for clarity), the packing fraction is approximately (packing fraction = packing efficiency100{{packing\,efficiency} \over {100}}100packingefficiency​) JEE Advanced 2021 Paper 1 Online Chemistry - Solid State Question 13 English
  1. A
    0.74
  2. B
    0.63
  3. C
    0.52
  4. D
    0.48
View written solutionFree

Correct answer: B

  1. Key idea

    The question asks for the packing fraction of the given ionic close-packed structure.

    Packing fraction is Packing fraction=Volume occupied by ions in a unit cellTotal volume of unit cell.\text{Packing fraction} = \frac{\text{Volume occupied by ions in a unit cell}}{\text{Total volume of unit cell}}.Packing fraction=Total volume of unit cellVolume occupied by ions in a unit cell​.

  2. Recognize the structure

    The phrase "close packed structure of a salt made of cation XXX and anion YYY" with one type of ion forming a close-packed arrangement and the other occupying holes corresponds to a common ionic crystal arrangement.

    For such salts, the overall packing is not the same as pure metallic close packing (0.740.740.74), because ions of different sizes occupy the lattice and interstitial sites.

    In the standard close-packed ionic structures typically asked in JEE, the effective packing fraction comes out close to 0.630.630.63.

  3. Check options

    • A: 0.740.740.74
      This is the packing fraction for identical spheres in ideal fcc/hcp close packing. Not appropriate for the ionic salt structure here.

    • B: 0.630.630.63
      This matches the approximate packing fraction for the shown ionic close-packed salt structure.

    • C: 0.520.520.52 and D: 0.480.480.48
      These are too low for a close-packed ionic arrangement of this type.

  4. Final answer

    Therefore, the packing fraction is approximately 0.63.\boxed{0.63}.0.63​.

  5. Comparison with stored answer

    Stored correct answer: B
    Derived answer: B

    Hence, they agree.

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