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Solid State question

2018 · Shift 1 · Q5
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  5. /2018 · Shift 1 · Q5

Solid State question

2018 · Shift 1 · Q5

JEE AdvancedChemistrySolid StateNumerical+3 / −1
Consider an ionic solid MXMXMX with NaClNaClNaCl structure. Construct a new structure (Z)(Z)(Z) whose unit cell is constructed from the unit cell of MXMXMX following the sequential instructions given below. Neglect the charge balance. (i)     (i)\,\,\,\,\,(i) Remove all the anions (X)(X)(X) except the central one (ii)    (ii)\,\,\,\,(ii) Replace all the face centered cations (M)(M)(M) by anions (X)(iii)  (X)(iii)\,\,(X)(iii) Remove all the corner cations (M)(iv)    (M)(iv)\,\,\,\,(M)(iv) Replace the central anion (X)(X)(X) with cation (M)(M)(M) The value of   (number  of  anionsnumber  of  cations)  \,\,\left( {{{number\,\,of\,\,anions} \over {number\,\,of\,\,cations}}} \right)\,\,(numberofcationsnumberofanions​) in ZZZ is ‾\underline{\hspace{2cm}}​.
Numerical answer
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