- AHydrated precipitates, when is bubbled through a solution of sodium aluminate.
- BAddition of lowers the melting point of alumina.
- Cis evolved at the anode during electrolysis.
- DThe cathode is a steel vessel with a lining or carbon.
View written solutionFree
Correct answer: A, B, C, D
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Identify the process involved
Extraction of aluminium from bauxite mainly involves:
- Purification of bauxite by Bayer’s process
- Electrolytic reduction of alumina by Hall–Héroult process
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Check statement A
In Bayer’s process, bauxite is treated with NaOH to form soluble sodium aluminate: or written as sodium aluminate solution.
When is passed through sodium aluminate solution, hydrated alumina precipitates:
So, A is true.
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Check statement B
In the Hall–Héroult process, pure alumina has a very high melting point (about ). To reduce the operating temperature, alumina is dissolved in molten cryolite, .
Thus, cryolite lowers the melting point of the mixture and improves conductivity.
So, B is true.
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Check statement C
During electrolysis, oxide ions are discharged at the carbon anode:
The oxygen formed reacts with the carbon anode:
Hence, is evolved at the anode (along with some CO in practice).
So, C is true.
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Check statement D
In the Hall–Héroult cell, the steel vessel lined with carbon acts as the cathode.
Therefore, D is true.
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Final evaluation
All four statements are correct:
- A: True
- B: True
- C: True
- D: True
So, the correct options are A, B, C, D.
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