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Isolation of Elements question

2020 · Shift 2 · Q9
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Isolation of Elements question

2020 · Shift 2 · Q9

JEE AdvancedChemistryIsolation of ElementsMultiple correct+4 / −2
Which among the following statement(s) is/are true for the extraction of aluminium from bauxite?
  1. A
    Hydrated Al2O3Al_2O_3Al2​O3​ precipitates, when CO2CO_2CO2​ is bubbled through a solution of sodium aluminate.
  2. B
    Addition of Na3AlF6Na_3AlF_6Na3​AlF6​ lowers the melting point of alumina.
  3. C
    CO2CO_2CO2​ is evolved at the anode during electrolysis.
  4. D
    The cathode is a steel vessel with a lining or carbon.
View written solutionFree

Correct answer: A, B, C, D

  1. Identify the process involved

    Extraction of aluminium from bauxite mainly involves:

    • Purification of bauxite by Bayer’s process
    • Electrolytic reduction of alumina by Hall–Héroult process

  1. Check statement A

    In Bayer’s process, bauxite is treated with NaOH to form soluble sodium aluminate: Al2O3+2NaOH+3H2O→2Na[Al(OH)4]Al_2O_3 + 2NaOH + 3H_2O \rightarrow 2Na[Al(OH)_4]Al2​O3​+2NaOH+3H2​O→2Na[Al(OH)4​] or written as sodium aluminate solution.

    When CO2CO_2CO2​ is passed through sodium aluminate solution, hydrated alumina precipitates: 2NaAlO2+CO2+3H2O→Al2O3⋅xH2O+Na2CO32NaAlO_2 + CO_2 + 3H_2O \rightarrow Al_2O_3\cdot xH_2O + Na_2CO_32NaAlO2​+CO2​+3H2​O→Al2​O3​⋅xH2​O+Na2​CO3​

    So, A is true.


  1. Check statement B

    In the Hall–Héroult process, pure alumina has a very high melting point (about 2050∘C2050^\circ C2050∘C). To reduce the operating temperature, alumina is dissolved in molten cryolite, Na3AlF6Na_3AlF_6Na3​AlF6​.

    Thus, cryolite lowers the melting point of the mixture and improves conductivity.

    So, B is true.


  1. Check statement C

    During electrolysis, oxide ions are discharged at the carbon anode: 2O2−→O2+4e−2O^{2-} \rightarrow O_2 + 4e^-2O2−→O2​+4e−

    The oxygen formed reacts with the carbon anode: C+O2→CO2C + O_2 \rightarrow CO_2C+O2​→CO2​

    Hence, CO2CO_2CO2​ is evolved at the anode (along with some CO in practice).

    So, C is true.


  1. Check statement D

    In the Hall–Héroult cell, the steel vessel lined with carbon acts as the cathode.

    Therefore, D is true.


  1. Final evaluation

    All four statements are correct:

    • A: True
    • B: True
    • C: True
    • D: True

So, the correct options are A, B, C, D.

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