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Electrochemistry question

2024 · Shift 1 · Q14
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  5. /2024 · Shift 1 · Q14

Electrochemistry question

2024 · Shift 1 · Q14

JEE AdvancedChemistryElectrochemistryMCQ+3 / −1

In a conductometric titration, small volume of titrant of higher concentration is added stepwise to a larger volume of titrate of much lower concentration, and the conductance is measured after each addition.

The limiting ionic conductivity (Λ0)\left(\Lambda_0\right)(Λ0​) values (in mSm2 mol−1\mathrm{mS} \mathrm{m}{ }^2 \mathrm{~mol}^{-1}mSm2 mol−1 ) for different ions in aqueous solutions are given below:

 Ions Ag+K+Na+H+NO3−Cl−SO42−OH−CH3COO−Λ06.27.45.035.07.27.616.019.94.1\begin{array}{|c|c|c|c|c|c|c|c|c|c|} \hline \text { Ions } & \mathrm{Ag}^{+} & \mathrm{K}^{+} & \mathrm{Na}^{+} & \mathrm{H}^{+} & \mathrm{NO}_3^{-} & \mathrm{Cl}^{-} & \mathrm{SO}_4^{2-} & \mathrm{OH}^{-} & \mathrm{CH}_3 \mathrm{COO}^{-} \\ \hline \Lambda_0 & 6.2 & 7.4 & 5.0 & 35.0 & 7.2 & 7.6 & 16.0 & 19.9 & 4.1 \\ \hline \end{array} Ions Λ0​​Ag+6.2​K+7.4​Na+5.0​H+35.0​NO3−​7.2​Cl−7.6​SO42−​16.0​OH−19.9​CH3​COO−4.1​​

For different combinations of titrates and titrants given in List-I, the graphs of 'conductance' versus 'volume of titrant' are given in List-II.

Match each entry in List-I with the appropriate entry in List-II and choose the correct option.

LIST-I LIST-II
(P) Titrate: KClKClKCl
Titrant: AgNO3AgNO_3AgNO3​
JEE Advanced 2024 Paper 1 Online Chemistry - Electrochemistry Question 3 English 1
(Q) Titrate: AgNO3AgNO_3AgNO3​
Titrant: KClKClKCl
JEE Advanced 2024 Paper 1 Online Chemistry - Electrochemistry Question 3 English 2
(R) Titrate: NaOHNaOHNaOH
Titrant: HClHClHCl
JEE Advanced 2024 Paper 1 Online Chemistry - Electrochemistry Question 3 English 3
(S) Titrate: NaOHNaOHNaOH
Titrant: CH3COOHCH_3COOHCH3​COOH
JEE Advanced 2024 Paper 1 Online Chemistry - Electrochemistry Question 3 English 4
JEE Advanced 2024 Paper 1 Online Chemistry - Electrochemistry Question 3 English 5
  1. A
    P-4, Q-3, R-2, S-5
  2. B
    P-2, Q-4, R-3, S-1
  3. C
    P-3, Q-4, R-2, S-5
  4. D
    P-4, Q-3, R-2, S-1
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