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Electrochemistry question

2025 · Shift 2 · Q14
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Electrochemistry question

2025 · Shift 2 · Q14

JEE AdvancedChemistryElectrochemistryNumerical+4 / −1
An electrochemical cell is fueled by the combustion of butane at 1 bar and 298 K . Its cell potential is XF×103\frac{\boldsymbol{X}}{F} \times 10^3FX​×103 volts, where FFF is the Faraday constant. The value of X\boldsymbol{X}X is ‾\underline{\hspace{2cm}}​. Use: Standard Gibbs energies of formation at 298 K are: ΔfGCO2o=−394 kJ mol−1;ΔfGwater o=−237 kJ mol−1;ΔfGbutane o=−18 kJ mol−1\Delta_f G_{\mathrm{CO}_2}^o=-394 \mathrm{~kJ} \mathrm{~mol}^{-1} ; \Delta_f G_{\text {water }}^o=-237 \mathrm{~kJ} \mathrm{~mol}^{-1} ; \Delta_f G_{\text {butane }}^o=-18 \mathrm{~kJ} \mathrm{~mol}^{-1}Δf​GCO2​o​=−394 kJ mol−1;Δf​Gwater o​=−237 kJ mol−1;Δf​Gbutane o​=−18 kJ mol−1
Numerical answer
View written solutionFree

Correct answer: 105.4TO105.6

  1. Write the combustion reaction of butane

For butane, C4H10\mathrm{C_4H_{10}}C4​H10​, the balanced combustion reaction is:

C4H10+132O2→4CO2+5H2O\mathrm{C_4H_{10} + \frac{13}{2}O_2 \rightarrow 4CO_2 + 5H_2O}C4​H10​+213​O2​→4CO2​+5H2​O

  1. Find standard Gibbs energy change of the reaction

Using

ΔrG∘=∑ν ΔfG∘(products)−∑ν ΔfG∘(reactants)\Delta_r G^\circ = \sum \nu \, \Delta_f G^\circ(\text{products}) - \sum \nu \, \Delta_f G^\circ(\text{reactants})Δr​G∘=∑νΔf​G∘(products)−∑νΔf​G∘(reactants)

Given:

ΔfG∘(CO2)=−394 kJ mol−1\Delta_f G^\circ(\mathrm{CO_2})=-394\ \text{kJ mol}^{-1}Δf​G∘(CO2​)=−394 kJ mol−1 ΔfG∘(H2O)=−237 kJ mol−1\Delta_f G^\circ(\mathrm{H_2O})=-237\ \text{kJ mol}^{-1}Δf​G∘(H2​O)=−237 kJ mol−1 ΔfG∘(C4H10)=−18 kJ mol−1\Delta_f G^\circ(\mathrm{C_4H_{10}})=-18\ \text{kJ mol}^{-1}Δf​G∘(C4​H10​)=−18 kJ mol−1 ΔfG∘(O2)=0\Delta_f G^\circ(\mathrm{O_2})=0Δf​G∘(O2​)=0

So,

ΔrG∘=[4(−394)+5(−237)]−[(−18)+0]\Delta_r G^\circ = [4(-394) + 5(-237)] - [(-18) + 0]Δr​G∘=[4(−394)+5(−237)]−[(−18)+0]

=(−1576−1185)+18= (-1576 - 1185) + 18=(−1576−1185)+18

=−2761+18=−2743 kJ mol−1= -2761 + 18 = -2743\ \text{kJ mol}^{-1}=−2761+18=−2743 kJ mol−1

Thus,

ΔrG∘=−2743×103 J mol−1\Delta_r G^\circ = -2743 \times 10^3\ \text{J mol}^{-1}Δr​G∘=−2743×103 J mol−1

  1. Relate Gibbs energy to cell potential

For an electrochemical cell,

ΔrG∘=−nFE∘\Delta_r G^\circ = -nFE^\circΔr​G∘=−nFE∘

We need nnn, the number of electrons transferred per mole of butane.

  1. Calculate number of electrons transferred

In C4H10\mathrm{C_4H_{10}}C4​H10​:

  • Let oxidation state of carbon be xxx.
  • For neutral molecule:

4x+10(+1)=04x + 10(+1) = 04x+10(+1)=0 4x+10=0⇒x=−524x + 10 = 0 \Rightarrow x = -\frac{5}{2}4x+10=0⇒x=−25​

Each carbon goes from −52-\frac{5}{2}−25​ in butane to +4+4+4 in CO2\mathrm{CO_2}CO2​. Change per carbon:

4−(−52)=1324 - \left(-\frac{5}{2}\right) = \frac{13}{2}4−(−25​)=213​

For 4 carbons, total electrons lost:

4×132=264 \times \frac{13}{2} = 264×213​=26

So, n=26n=26n=26.

  1. Compute the cell potential

E∘=−ΔrG∘nF=2743×10326FE^\circ = \frac{-\Delta_r G^\circ}{nF} = \frac{2743\times 10^3}{26F}E∘=nF−Δr​G∘​=26F2743×103​

E∘=105.5F×103 VE^\circ = \frac{105.5}{F}\times 10^3\ \text{V}E∘=F105.5​×103 V

Hence,

X=274326=105.5X = \frac{2743}{26} = 105.5X=262743​=105.5

  1. Final integer-type value

X≈105.5\boxed{X \approx 105.5}X≈105.5​

Since the stored correct answer range is 105.4105.4105.4 to 105.6105.6105.6, this matches.

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