JEE AdvancedChemistryElectrochemistryNumerical+4 / −1
An electrochemical cell is fueled by the combustion of butane at 1 bar and 298 K . Its cell potential is volts, where is the Faraday constant. The value of is . Use: Standard Gibbs energies of formation at 298 K are:
Numerical answer
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Correct answer: 105.4TO105.6
- Write the combustion reaction of butane
For butane, , the balanced combustion reaction is:
- Find standard Gibbs energy change of the reaction
Using
Given:
So,
Thus,
- Relate Gibbs energy to cell potential
For an electrochemical cell,
We need , the number of electrons transferred per mole of butane.
- Calculate number of electrons transferred
In :
- Let oxidation state of carbon be .
- For neutral molecule:
Each carbon goes from in butane to in . Change per carbon:
For 4 carbons, total electrons lost:
So, .
- Compute the cell potential
Hence,
- Final integer-type value
Since the stored correct answer range is to , this matches.
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