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Chemical Kinetics and Nuclear Chemistry question

2016 · Shift 1 · Q1
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Chemical Kinetics and Nuclear Chemistry question

2016 · Shift 1 · Q1

JEE AdvancedChemistryChemical Kinetics and Nuclear ChemistryMultiple correct+4 / −2
A plot of the number of neutrons (N) against the number of protons (P) of stable nuclei exhibits upward deviation from linearity for atomic number, Z > 20. For an unstable nucleus having N/P ratio less than 1, the possible mode(s) of decay is(are)
  1. A
    β−\beta ^-β−-decay ( β\betaβ emission)
  2. B
    orbital or K-electron capture
  3. C
    neutron emission
  4. D
    β+\beta ^+β+-decay (positron emission)
View written solutionFree

Correct answer: B, D

  1. Interpret the nuclear composition condition

    For the given unstable nucleus, NP<1\frac{N}{P} < 1PN​<1 This means the nucleus is proton-rich (or neutron-deficient), since the number of neutrons is less than the number of protons.

  2. Recall how different decay modes change NNN and PPP

    We examine each option by seeing whether it helps a proton-rich nucleus move toward stability.


    (A) β−\beta^-β− decay

    In β−\beta^-β− decay: n→p+e−+νˉn \to p + e^- + \bar\nun→p+e−+νˉ So,

    • NNN decreases by 1
    • PPP increases by 1

    Hence N/PN/PN/P decreases even further. A proton-rich nucleus does not prefer this mode.

    Therefore, A is incorrect.


    (B) Orbital or K-electron capture

    In electron capture: p+e−→n+νp + e^- \to n + \nup+e−→n+ν So,

    • PPP decreases by 1
    • NNN increases by 1

    This increases the N/PN/PN/P ratio and helps a proton-rich nucleus approach stability.

    Therefore, B is correct.


    (C) Neutron emission

    In neutron emission:

    • NNN decreases by 1
    • PPP unchanged

    This makes the nucleus even more neutron-deficient, so it moves away from stability when N/P<1N/P < 1N/P<1.

    Therefore, C is incorrect.


    (D) β+\beta^+β+ decay (positron emission)

    In β+\beta^+β+ decay: p→n+e++νp \to n + e^+ + \nup→n+e++ν So,

    • PPP decreases by 1
    • NNN increases by 1

    Again, this raises N/PN/PN/P and helps the proton-rich nucleus move toward stability.

    Therefore, D is correct.

  3. Final selection

    The possible decay modes for a nucleus with NP<1\frac{N}{P} < 1PN​<1 are: B, D\boxed{\text{B, D}}B, D​

  4. Comparison with stored correct answer

    Stored correct answer: B, D

    Our derived answer: B, D

    Hence, the derived answer agrees with the stored answer.

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