The equation of state of a real gas is given by $$\left(\mathrm{P}+\frac{\mathrm{a}}{\mathrm{V}^2}\right)(\mathrm{V}-\mathrm{b})=\mathrm{RT}$$, where $\mathrm{P}, \mathrm{V}$ and $\mathrm{T}$ are pressure, volume and temperature respectively and $\mathrm{R}$ is the universal gas constant. The dimensions of $\frac{\mathrm{a}}{\mathrm{b}^2}$ is similar to that of :