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Heat and Thermodynamics question

2024 · 27 Jan · Shift 2 · Q70
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Heat and Thermodynamics question

2024 · 27 Jan · Shift 2 · Q70

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
During an adiabatic process, the pressure of a gas is found to be proportional to the cube of its absolute temperature. The ratio of CpCv\frac{\mathrm{Cp}}{\mathrm{Cv}}CvCp​ for the gas is :
  1. A
    75\frac{7}{5}57​
  2. B
    32\frac{3}{2}23​
  3. C
    97\frac{9}{7}79​
  4. D
    53\frac{5}{3}35​
View written solutionFree

Correct answer: B

  1. Use the adiabatic relation

For an ideal gas in an adiabatic process, PVγ=constantPV^\gamma = \text{constant}PVγ=constant where γ=CpCv.\gamma = \frac{C_p}{C_v}.γ=Cv​Cp​​.

Also, from the ideal gas law, PV=nRT.PV = nRT.PV=nRT. So we can derive the relation between PPP and TTT during an adiabatic process.

  1. Find the standard relation between PPP and TTT in adiabatic change

From PVγ=constantPV^\gamma = \text{constant}PVγ=constant and V=nRTP,V = \frac{nRT}{P},V=PnRT​, substitute VVV into the adiabatic equation:

P(nRTP)γ=constant.P\left(\frac{nRT}{P}\right)^\gamma = \text{constant}.P(PnRT​)γ=constant.

Simplifying, P⋅(nR)γTγPγ=constantP \cdot \frac{(nR)^\gamma T^\gamma}{P^\gamma} = \text{constant}P⋅Pγ(nR)γTγ​=constant (nR)γTγP1−γ=constant.(nR)^\gamma T^\gamma P^{1-\gamma} = \text{constant}.(nR)γTγP1−γ=constant.

Since (nR)γ(nR)^\gamma(nR)γ is constant, TγP1−γ=constant.T^\gamma P^{1-\gamma} = \text{constant}.TγP1−γ=constant.

Rearranging, Pγ−1∝Tγ.P^{\gamma-1} \propto T^\gamma.Pγ−1∝Tγ.

Hence, P∝Tγγ−1.P \propto T^{\frac{\gamma}{\gamma-1}}.P∝Tγ−1γ​.

  1. Use the given condition

The question says: P∝T3.P \propto T^3.P∝T3.

So, γγ−1=3.\frac{\gamma}{\gamma-1} = 3.γ−1γ​=3.

  1. Solve for γ\gammaγ

γ=3(γ−1)\gamma = 3(\gamma-1)γ=3(γ−1) γ=3γ−3\gamma = 3\gamma - 3γ=3γ−3 2γ=32\gamma = 32γ=3 γ=32.\gamma = \frac{3}{2}.γ=23​.

Therefore, CpCv=32.\frac{C_p}{C_v} = \frac{3}{2}. Cv​Cp​​=23​.

  1. Check options
  • A: 75\frac{7}{5}57​
  • B: 32\frac{3}{2}23​
  • C: 97\frac{9}{7}79​
  • D: 53\frac{5}{3}35​

So the correct option is B.

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