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Heat and Thermodynamics question

2024 · 8 Apr · Shift 2 · Q74
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Heat and Thermodynamics question

2024 · 8 Apr · Shift 2 · Q74

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
Given below are two statements : Statement (I) : The mean free path of gas molecules is inversely proportional to square of molecular diameter. Statement (II) : Average kinetic energy of gas molecules is directly proportional to absolute temperature of gas. In the light of the above statements, choose the correct answer from the options given below :
  1. A
    Statement I is false but Statement II is true
  2. B
    Both Statement I and Statement II are true
  3. C
    Statement I is true but Statement II is false
  4. D
    Both Statement I and Statement II are false
View written solutionFree

Correct answer: B

  1. Check Statement (I): Mean free path

For an ideal gas, the mean free path λ\lambdaλ is given by

λ=12 πd2n\lambda = \frac{1}{\sqrt{2}\,\pi d^2 n}λ=2​πd2n1​

where:

  • ddd = molecular diameter
  • nnn = number of molecules per unit volume

From this expression,

λ∝1d2\lambda \propto \frac{1}{d^2}λ∝d21​

So, the mean free path is inversely proportional to the square of molecular diameter.

Therefore, Statement (I) is true.


  1. Check Statement (II): Average kinetic energy

The average kinetic energy of one gas molecule is

Eˉ=32kT\bar{E} = \frac{3}{2}kTEˉ=23​kT

where:

  • kkk = Boltzmann constant
  • TTT = absolute temperature

Thus,

Eˉ∝T\bar{E} \propto TEˉ∝T

So, the average kinetic energy of gas molecules is directly proportional to absolute temperature.

Therefore, Statement (II) is true.


  1. Choose the correct option
  • Statement (I): True
  • Statement (II): True

Hence, the correct option is:

B\boxed{\text{B}}B​
  1. Comparison with stored correct answer

Stored correct answer: B\text{B}B

My derived answer: B\text{B}B

They match.

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