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Heat and Thermodynamics question

2023 · 31 Jan · Shift 2 · Q46
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  5. /2023 · 31 Jan · Shift 2 · Q46

Heat and Thermodynamics question

2023 · 31 Jan · Shift 2 · Q46

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
Heat energy of 735 J735 \mathrm{~J}735 J is given to a diatomic gas allowing the gas to expand at constant pressure. Each gas molecule rotates around an internal axis but do not oscillate. The increase in the internal energy of the gas will be :
  1. A
    572 J572 \mathrm{~J}572 J
  2. B
    441 J441 \mathrm{~J}441 J
  3. C
    525 J525 \mathrm{~J}525 J
  4. D
    735 J735 \mathrm{~J}735 J
View written solutionFree

Correct answer: C

  1. Identify the degrees of freedom

For a diatomic gas in this condition:

  • translational degrees of freedom =3=3=3
  • rotational degrees of freedom =2=2=2 (about two axes perpendicular to the bond)
  • vibrational degrees of freedom are neglected

So total active degrees of freedom: f=3+2=5f=3+2=5f=3+2=5

Hence, CV=f2R=52RC_V=\frac{f}{2}R=\frac{5}{2}RCV​=2f​R=25​R

and CP=CV+R=72RC_P=C_V+R=\frac{7}{2}RCP​=CV​+R=27​R

  1. Use the relation for heat supplied at constant pressure

At constant pressure, Q=nCPΔTQ=nC_P\Delta TQ=nCP​ΔT

The increase in internal energy is ΔU=nCVΔT\Delta U=nC_V\Delta TΔU=nCV​ΔT

Therefore, ΔU=CVCPQ\Delta U=\frac{C_V}{C_P}QΔU=CP​CV​​Q

Substitute the values:

=\frac{5}{7}\times 735$$ 3. **Calculate** $$\Delta U=5\times 105=525\,\text{J}$$ 4. **Check options** - A: $572\,\text{J}$ ❌ - B: $441\,\text{J}$ ❌ - C: $525\,\text{J}$ ✅ - D: $735\,\text{J}$ ❌ So the correct answer is **Option C**.
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