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Heat and Thermodynamics question

2022 · 29 Jun · Shift 2 · Q50
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Heat and Thermodynamics question

2022 · 29 Jun · Shift 2 · Q50

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
Starting with the same initial conditions, an ideal gas expands from volume V1 to V2 in three different ways. The work done by the gas is W1 if the process is purely isothermal, W2, if the process is purely adiabatic and W3 if the process is purely isobaric. Then, choose the correct option
  1. A
    W1 2 3
  2. B
    W2 3 1
  3. C
    W3 1 2
  4. D
    W2 1 3
View written solutionFree

Correct answer: D

  1. Given: An ideal gas starts from the same initial state and expands from volume V1V_1V1​ to V2V_2V2​ by three different processes:

    • Isothermal: work W1W_1W1​
    • Adiabatic: work W2W_2W2​
    • Isobaric: work W3W_3W3​

    We must compare W1,W2,W3W_1, W_2, W_3W1​,W2​,W3​.

  2. Work done in each process

    Work done by a gas is W=∫V1V2P dVW = \int_{V_1}^{V_2} P\,dVW=∫V1​V2​​PdV

    So the comparison depends on the pressure-volume curve for each process.

  3. Isobaric process

    For isobaric expansion, pressure remains constant at the initial pressure P1P_1P1​: W3=P1(V2−V1)W_3 = P_1 (V_2 - V_1)W3​=P1​(V2​−V1​)

  4. Isothermal process

    For isothermal expansion of an ideal gas, P=nRTV=P1V1VP = \frac{nRT}{V} = \frac{P_1V_1}{V}P=VnRT​=VP1​V1​​ Hence, W1=∫V1V2P1V1VdV=P1V1ln⁡(V2V1)W_1 = \int_{V_1}^{V_2} \frac{P_1V_1}{V} dV = P_1V_1 \ln\left(\frac{V_2}{V_1}\right)W1​=∫V1​V2​​VP1​V1​​dV=P1​V1​ln(V1​V2​​)

  5. Adiabatic process

    For adiabatic expansion, PVγ=constantPV^\gamma = \text{constant}PVγ=constant so pressure falls faster with volume than in the isothermal case. Therefore, for every intermediate volume between V1V_1V1​ and V2V_2V2​, Padiabatic<Pisothermal<PisobaricP_{\text{adiabatic}} < P_{\text{isothermal}} < P_{\text{isobaric}}Padiabatic​<Pisothermal​<Pisobaric​

    Since work is the area under the PPP–VVV curve from V1V_1V1​ to V2V_2V2​, W2<W1<W3W_2 < W_1 < W_3W2​<W1​<W3​

  6. Direct mathematical check

    Let x=V2V1>1x = \frac{V_2}{V_1} > 1x=V1​V2​​>1

    Then W3=P1V1(x−1)W_3 = P_1V_1(x-1)W3​=P1​V1​(x−1) W1=P1V1ln⁡xW_1 = P_1V_1\ln xW1​=P1​V1​lnx

    Since for x>1x>1x>1, ln⁡x<x−1\ln x < x-1lnx<x−1 we get W1<W3W_1 < W_3W1​<W3​

    Also, adiabatic curve lies below isothermal during expansion, so W2<W1W_2 < W_1W2​<W1​

    Therefore, W2<W1<W3W_2 < W_1 < W_3W2​<W1​<W3​

  7. Matching with options

    This ordering means:

    • smallest: W2W_2W2​
    • middle: W1W_1W1​
    • largest: W3W_3W3​

    So the correct option is D.

  8. Comparison with stored answer

    Stored correct answer: D

    This matches our derived answer.

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