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Heat and Thermodynamics question

2021 · 16 Mar · Shift 1 · Q61
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Heat and Thermodynamics question

2021 · 16 Mar · Shift 1 · Q61

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
The volume V of an enclosure contains a mixture of three gases, 16 g of oxygen, 28 g of nitrogen and 44 g of carbon dioxide at absolute temperature T. Consider R as universal gas constant. The pressure of the mixture of gases is :
  1. A
    3RTV{{3RT} \over V}V3RT​
  2. B
    4RTV{{4RT} \over V}V4RT​
  3. C
    88RTV{{88RT} \over V}V88RT​
  4. D
    52RTV{5 \over 2}{{RT} \over V}25​VRT​
View written solutionFree

Correct answer: D

  1. Use Dalton’s law / ideal gas law for a mixture

For a mixture of ideal gases in volume VVV at temperature TTT,

PV=ntotalRTP V = n_{\text{total}} R TPV=ntotal​RT

So,

P=ntotalRTVP = \frac{n_{\text{total}}RT}{V}P=Vntotal​RT​

Thus we only need the total number of moles.


  1. Calculate moles of each gas
  • Oxygen: given mass =16 g=16\,\text{g}=16g, molar mass of O2=32 g mol−1O_2 = 32\,\text{g mol}^{-1}O2​=32g mol−1

nO2=1632=12n_{O_2} = \frac{16}{32} = \frac{1}{2}nO2​​=3216​=21​

  • Nitrogen: given mass =28 g=28\,\text{g}=28g, molar mass of N2=28 g mol−1N_2 = 28\,\text{g mol}^{-1}N2​=28g mol−1

nN2=2828=1n_{N_2} = \frac{28}{28} = 1nN2​​=2828​=1

  • Carbon dioxide: given mass =44 g=44\,\text{g}=44g, molar mass of CO2=44 g mol−1CO_2 = 44\,\text{g mol}^{-1}CO2​=44g mol−1

nCO2=4444=1n_{CO_2} = \frac{44}{44} = 1nCO2​​=4444​=1


  1. Find total moles

ntotal=12+1+1=52n_{\text{total}} = \frac{1}{2} + 1 + 1 = \frac{5}{2}ntotal​=21​+1+1=25​


  1. Compute pressure

Using

P=ntotalRTVP = \frac{n_{\text{total}}RT}{V}P=Vntotal​RT​

we get

P=(52)RTV=5RT2VP = \frac{\left(\frac{5}{2}\right)RT}{V} = \frac{5RT}{2V}P=V(25​)RT​=2V5RT​


  1. Match with options

5RT2V=52RTV\frac{5RT}{2V} = \frac{5}{2}\frac{RT}{V}2V5RT​=25​VRT​

This matches Option D.


  1. Comparison with stored answer

Stored correct answer: D
Derived answer: D

So the derived answer agrees with the stored answer.

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