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Heat and Thermodynamics question

2021 · 26 Aug · Shift 1 · Q56
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Heat and Thermodynamics question

2021 · 26 Aug · Shift 1 · Q56

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
The rms speeds of the molecules of Hydrogen, Oxygen and Carbon dioxide at the same temperature are VH, VO and VC respectively then :
  1. A
    VH > VO > VC
  2. B
    VC > VO > VH
  3. C
    VH = VO > VC
  4. D
    VH = VO = VC
View written solutionFree

Correct answer: A

  1. For a gas at temperature TTT, the root mean square speed is

vrms=3RTMv_{\text{rms}}=\sqrt{\frac{3RT}{M}}vrms​=M3RT​​

where MMM is the molar mass of the gas.

  1. Since all three gases are at the same temperature, and 3RT3RT3RT is the same for all, we have

vrms∝1Mv_{\text{rms}} \propto \frac{1}{\sqrt{M}}vrms​∝M​1​

So, smaller molar mass means greater rms speed.

  1. Molar masses:
  • Hydrogen H2H_2H2​: MH=2M_H = 2MH​=2
  • Oxygen O2O_2O2​: MO=32M_O = 32MO​=32
  • Carbon dioxide CO2CO_2CO2​: MC=44M_C = 44MC​=44
  1. Compare speeds using inverse square root dependence:

vH∝12,vO∝132,vC∝144v_H \propto \frac{1}{\sqrt{2}}, \quad v_O \propto \frac{1}{\sqrt{32}}, \quad v_C \propto \frac{1}{\sqrt{44}}vH​∝2​1​,vO​∝32​1​,vC​∝44​1​

Since

2<32<442 < 32 < 442<32<44

therefore

12>132>144\frac{1}{\sqrt{2}} > \frac{1}{\sqrt{32}} > \frac{1}{\sqrt{44}}2​1​>32​1​>44​1​

Hence,

VH>VO>VCV_H > V_O > V_CVH​>VO​>VC​

  1. Option check:
  • A: VH>VO>VCV_H > V_O > V_CVH​>VO​>VC​ ✅
  • B: VC>VO>VHV_C > V_O > V_HVC​>VO​>VH​ ❌
  • C: VH=VO>VCV_H = V_O > V_CVH​=VO​>VC​ ❌
  • D: VH=VO=VCV_H = V_O = V_CVH​=VO​=VC​ ❌

Therefore, the correct option is A.

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