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Heat and Thermodynamics question

2021 · 17 Mar · Shift 1 · Q45
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  5. /2021 · 17 Mar · Shift 1 · Q45

Heat and Thermodynamics question

2021 · 17 Mar · Shift 1 · Q45

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
Two ideal polyatomic gases at temperatures T1 and T2 are mixed so that there is no loss of energy. If F1 and F2, m1 and m2, n1 and n2 be the degrees of freedom, masses, number of molecules of the first and second gas respectively, the temperature of mixture of these two gases is :
  1. A
    n1F1T1+n2F2T2F1+F2{{{n_1}{F_1}{T_1} + {n_2}{F_2}{T_2}} \over {{F_1} + {F_2}}}F1​+F2​n1​F1​T1​+n2​F2​T2​​
  2. B
    n1F1T1+n2F2T2n1F1+n2F2{{{n_1}{F_1}{T_1} + {n_2}{F_2}{T_2}} \over {{n_1}{F_1} + {n_2}{F_2}}}n1​F1​+n2​F2​n1​F1​T1​+n2​F2​T2​​
  3. C
    n1T1+n2T2n1+n2{{{n_1}{T_1} + {n_2}{T_2}} \over {{n_1} + {n_2}}}n1​+n2​n1​T1​+n2​T2​​
  4. D
    n1F1T1+n2F2T2n1+n2{{{n_1}{F_1}{T_1} + {n_2}{F_2}{T_2}} \over {{n_1} + {n_2}}}n1​+n2​n1​F1​T1​+n2​F2​T2​​
View written solutionFree

Correct answer: B

  1. Use internal energy of an ideal gas

For an ideal gas with degrees of freedom FFF, number of molecules nnn, and temperature TTT, the total internal energy is

U=F2nkTU = \frac{F}{2} n k TU=2F​nkT

where kkk is Boltzmann constant.

  1. Write initial total energy of the two gases

For the first gas,

U1=F12n1kT1U_1 = \frac{F_1}{2} n_1 k T_1U1​=2F1​​n1​kT1​

For the second gas,

U2=F22n2kT2U_2 = \frac{F_2}{2} n_2 k T_2U2​=2F2​​n2​kT2​

So initial total energy is

Uinitial=k2(n1F1T1+n2F2T2)U_{\text{initial}} = \frac{k}{2}(n_1F_1T_1 + n_2F_2T_2)Uinitial​=2k​(n1​F1​T1​+n2​F2​T2​)

  1. After mixing

Since there is no loss of energy, total internal energy remains conserved.

Let final temperature of mixture be TTT.

Then total internal energy of the mixture is

Ufinal=F12n1kT+F22n2kTU_{\text{final}} = \frac{F_1}{2} n_1 k T + \frac{F_2}{2} n_2 k TUfinal​=2F1​​n1​kT+2F2​​n2​kT

Ufinal=k2(n1F1+n2F2)TU_{\text{final}} = \frac{k}{2}(n_1F_1 + n_2F_2)TUfinal​=2k​(n1​F1​+n2​F2​)T

  1. Apply conservation of energy

Uinitial=UfinalU_{\text{initial}} = U_{\text{final}}Uinitial​=Ufinal​

k2(n1F1T1+n2F2T2)=k2(n1F1+n2F2)T\frac{k}{2}(n_1F_1T_1 + n_2F_2T_2) = \frac{k}{2}(n_1F_1 + n_2F_2)T2k​(n1​F1​T1​+n2​F2​T2​)=2k​(n1​F1​+n2​F2​)T

Cancel k2\frac{k}{2}2k​:

n1F1T1+n2F2T2=(n1F1+n2F2)Tn_1F_1T_1 + n_2F_2T_2 = (n_1F_1 + n_2F_2)Tn1​F1​T1​+n2​F2​T2​=(n1​F1​+n2​F2​)T

Hence,

T=n1F1T1+n2F2T2n1F1+n2F2T = \frac{n_1F_1T_1 + n_2F_2T_2}{n_1F_1 + n_2F_2}T=n1​F1​+n2​F2​n1​F1​T1​+n2​F2​T2​​

  1. Match with options

This matches Option B.

  1. Check note about masses

The masses m1,m2m_1, m_2m1​,m2​ are irrelevant here because internal energy of an ideal gas depends on temperature and degrees of freedom, not directly on molecular mass.

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