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Heat and Thermodynamics question

2019 · 8 Apr · Shift 1 · Q50
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Heat and Thermodynamics question

2019 · 8 Apr · Shift 1 · Q50

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
A thermally insulated vessel contains 150g of water at 0°C. Then the air from the vessel is pumped out adiabatically. A fraction of water turns into ice and the rest evaporates at 0°C itself. The mass of evaporated water will be closest to : (Latent heat of vaporization of water = 2.10 × 106 J kg–1 and Latent heat of Fusion of water = 3.36 × 105 J kg–1)
  1. A
    35 g
  2. B
    130 g
  3. C
    20 g
  4. D
    150 g
View written solutionFree

Correct answer: C

  1. Physical idea

    The vessel is thermally insulated, so no heat is exchanged with surroundings.

    When air is pumped out adiabatically, some water evaporates at 0∘C0^\circ\text{C}0∘C, requiring latent heat of vaporization. Since no external heat is available, this heat must come from the water itself.

    Therefore, another part of the water freezes at 0∘C0^\circ\text{C}0∘C and releases latent heat of fusion.

    So, in equilibrium: heat released by freezing=heat absorbed in evaporation\text{heat released by freezing} = \text{heat absorbed in evaporation}heat released by freezing=heat absorbed in evaporation

  2. Let masses be

    Let

    • mass of water frozen =mf= m_f=mf​
    • mass of water evaporated =me= m_e=me​

    Initial mass of water =150 g=0.150 kg=150\,\text{g}=0.150\,\text{kg}=150g=0.150kg.

  3. Apply energy balance

    Heat released by freezing: Qfreeze=mfLfQ_{\text{freeze}} = m_f L_fQfreeze​=mf​Lf​

    Heat absorbed by evaporation: Qevap=meLvQ_{\text{evap}} = m_e L_vQevap​=me​Lv​

    Hence, mfLf=meLvm_f L_f = m_e L_vmf​Lf​=me​Lv​

    Using Lf=3.36×105 J kg−1,Lv=2.10×106 J kg−1L_f = 3.36\times10^5\,\text{J kg}^{-1}, \qquad L_v = 2.10\times10^6\,\text{J kg}^{-1}Lf​=3.36×105J kg−1,Lv​=2.10×106J kg−1

    mf(3.36×105)=me(2.10×106)m_f(3.36\times10^5)=m_e(2.10\times10^6)mf​(3.36×105)=me​(2.10×106)

    mf=me(2.10×1063.36×105)=me(21033.6)=6.25mem_f = m_e\left(\frac{2.10\times10^6}{3.36\times10^5}\right)=m_e\left(\frac{210}{33.6}\right)=6.25m_emf​=me​(3.36×1052.10×106​)=me​(33.6210​)=6.25me​

  4. Use mass conservation

    Since finally some becomes ice and the rest evaporates, all the initial water is accounted for by these two parts: mf+me=0.150m_f + m_e = 0.150mf​+me​=0.150

    Substitute mf=6.25mem_f=6.25m_emf​=6.25me​: 6.25me+me=0.1506.25m_e + m_e = 0.1506.25me​+me​=0.150 7.25me=0.1507.25m_e = 0.1507.25me​=0.150 me=0.1507.25≈0.0207 kgm_e = \frac{0.150}{7.25} \approx 0.0207\,\text{kg}me​=7.250.150​≈0.0207kg

    me≈20.7 gm_e \approx 20.7\,\text{g}me​≈20.7g

  5. Closest option

    me≈21 gm_e \approx 21\,\text{g}me​≈21g

    Closest option is 20 g.

  6. Answer check with stored answer

    Derived answer: Option C (20 g).

    Stored correct answer: C.

    They match.

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