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Heat and Thermodynamics question

2019 · 8 Apr · Shift 2 · Q61
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Heat and Thermodynamics question

2019 · 8 Apr · Shift 2 · Q61

JEE MainPhysicsHeat and ThermodynamicsMCQ+4 / −1
The temperature, at which the root mean square velocity of hydrogen molecules equals their escape velocity from the earth, is closest to : [Boltzmann Constant kB = 1.38 × 10–23 J/K Avogadro Number NA = 6.02 × 1026 /kg Radius of Earth : 6.4 × 106 m Gravitational acceleration on Earth = 10ms–2]
  1. A
    3 × 105 K
  2. B
    104 K
  3. C
    650 K
  4. D
    800 K
View written solutionFree

Correct answer: B

  1. Use the escape velocity from Earth

The escape velocity is

ve=2gRv_e = \sqrt{2gR}ve​=2gR​

Given:

  • g=10 m s−2g = 10\,\text{m s}^{-2}g=10m s−2
  • R=6.4×106 mR = 6.4\times 10^6\,\text{m}R=6.4×106m

So,

ve=2×10×6.4×106v_e = \sqrt{2\times 10\times 6.4\times 10^6}ve​=2×10×6.4×106​

ve=1.28×108v_e = \sqrt{1.28\times 10^8}ve​=1.28×108​

ve≈1.13×104 m s−1v_e \approx 1.13\times 10^4\,\text{m s}^{-1}ve​≈1.13×104m s−1


  1. RMS speed of hydrogen molecules

For a gas,

vrms=3kBTmv_{\text{rms}} = \sqrt{\frac{3k_B T}{m}}vrms​=m3kB​T​​

We are told that the RMS speed of hydrogen molecules equals escape velocity:

3kBTm=ve\sqrt{\frac{3k_B T}{m}} = v_em3kB​T​​=ve​

Squaring both sides,

3kBTm=ve2\frac{3k_B T}{m} = v_e^2m3kB​T​=ve2​

T=mve23kBT = \frac{m v_e^2}{3k_B}T=3kB​mve2​​


  1. Mass of one hydrogen molecule

Hydrogen is H2H_2H2​, so its molar mass is

M=2×10−3 kg mol−1M = 2\times 10^{-3}\,\text{kg mol}^{-1}M=2×10−3kg mol−1

Mass of one molecule:

m=MNA=2×10−36.02×1023m = \frac{M}{N_A} = \frac{2\times 10^{-3}}{6.02\times 10^{23}}m=NA​M​=6.02×10232×10−3​

m≈3.32×10−27 kgm \approx 3.32\times 10^{-27}\,\text{kg}m≈3.32×10−27kg


  1. Substitute values

Using

ve2=1.28×108v_e^2 = 1.28\times 10^8ve2​=1.28×108

we get

T=(3.32×10−27)(1.28×108)3(1.38×10−23)T = \frac{(3.32\times 10^{-27})(1.28\times 10^8)}{3(1.38\times 10^{-23})}T=3(1.38×10−23)(3.32×10−27)(1.28×108)​

First calculate numerator:

3.32×1.28≈4.253.32\times 1.28 \approx 4.253.32×1.28≈4.25

⇒(3.32×10−27)(1.28×108)≈4.25×10−19\Rightarrow (3.32\times 10^{-27})(1.28\times 10^8) \approx 4.25\times 10^{-19}⇒(3.32×10−27)(1.28×108)≈4.25×10−19

Denominator:

3×1.38×10−23=4.14×10−233\times 1.38\times 10^{-23} = 4.14\times 10^{-23}3×1.38×10−23=4.14×10−23

Thus,

T≈4.25×10−194.14×10−23T \approx \frac{4.25\times 10^{-19}}{4.14\times 10^{-23}}T≈4.14×10−234.25×10−19​

T≈1.03×104 KT \approx 1.03\times 10^4\,\text{K}T≈1.03×104K


  1. Choose the closest option

T≈104 KT \approx 10^4\,\text{K}T≈104K

So the correct option is B.


  1. Comparison with stored answer

Stored correct answer: B

Our derived answer: B

They agree.

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