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Atoms and Nuclei question

2025 · 24 Jan · Shift 1 · Q55
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Atoms and Nuclei question

2025 · 24 Jan · Shift 1 · Q55

JEE MainPhysicsAtoms and NucleiMCQ+4 / −1
During the transition of electron from state A to state C of a Bohr atom, the wavelength of emitted radiation is 2000Ao2000 \mathop A\limits^o2000Ao​ and it becomes 6000Ao6000 \mathop A\limits^o6000Ao​ when the electron jumps from state B to state C. Then the wavelength of the radiation emitted during the transition of electrons from state A to state B is
  1. A
    4000Ao4000 \mathop A\limits^o4000Ao​
  2. B
    6000Ao6000 \mathop A\limits^o6000Ao​
  3. C
    2000Ao2000 \mathop A\limits^o2000Ao​
  4. D
    3000Ao3000 \mathop A\limits^o3000Ao​
View written solutionFree

Correct answer: D

  1. Use Bohr transition energy relation

For a transition between two energy levels, the emitted photon energy is

E=hν=hcλE = h\nu = \frac{hc}{\lambda}E=hν=λhc​

So, for the given transitions:

  • From A→CA \to CA→C: EAC=hc2000 A˚E_{AC} = \frac{hc}{2000\,\text{\AA}}EAC​=2000A˚hc​

  • From B→CB \to CB→C: EBC=hc6000 A˚E_{BC} = \frac{hc}{6000\,\text{\AA}}EBC​=6000A˚hc​

  1. Relate the energy levels

Let the energy levels be EA,EB,ECE_A, E_B, E_CEA​,EB​,EC​ with EA>EB>ECE_A > E_B > E_CEA​>EB​>EC​.

Then,

EAC=EA−ECE_{AC} = E_A - E_CEAC​=EA​−EC​ EBC=EB−ECE_{BC} = E_B - E_CEBC​=EB​−EC​

The transition from A→BA \to BA→B has energy

EAB=EA−EBE_{AB} = E_A - E_BEAB​=EA​−EB​

But,

EA−EB=(EA−EC)−(EB−EC)E_A - E_B = (E_A - E_C) - (E_B - E_C)EA​−EB​=(EA​−EC​)−(EB​−EC​)

So,

EAB=EAC−EBCE_{AB} = E_{AC} - E_{BC}EAB​=EAC​−EBC​

  1. Substitute the photon energies

hcλAB=hc2000−hc6000\frac{hc}{\lambda_{AB}} = \frac{hc}{2000} - \frac{hc}{6000}λAB​hc​=2000hc​−6000hc​

Cancel hchchc:

1λAB=12000−16000\frac{1}{\lambda_{AB}} = \frac{1}{2000} - \frac{1}{6000}λAB​1​=20001​−60001​

Take LCM:

1λAB=3−16000=26000=13000\frac{1}{\lambda_{AB}} = \frac{3-1}{6000} = \frac{2}{6000} = \frac{1}{3000}λAB​1​=60003−1​=60002​=30001​

Hence,

λAB=3000 A˚\lambda_{AB} = 3000\,\text{\AA}λAB​=3000A˚

  1. Match with options

3000 A˚\boxed{3000\,\text{\AA}}3000A˚​

So the correct option is D.

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