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Thermodynamics question

2024 · 6 Apr · Shift 1 · Q24
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Thermodynamics question

2024 · 6 Apr · Shift 1 · Q24

JEE MainChemistryThermodynamicsNumerical+4 / −1
An ideal gas, C‾v=52R\overline{\mathrm{C}}_{\mathrm{v}}=\frac{5}{2} \mathrm{R}Cv​=25​R, is expanded adiabatically against a constant pressure of 1 atm untill it doubles in volume. If the initial temperature and pressure is 298 K298 \mathrm{~K}298 K and 5 atm5 \mathrm{~atm}5 atm, respectively then the final temperature is ‾K\underline{\hspace{2cm}}\mathrm{K}​K (nearest integer). [c‾v\overline{\mathrm{c}}_{\mathrm{v}}cv​ is the molar heat capacity at constant volume]
Numerical answer
View written solutionFree

Correct answer: 274

  1. Given data
  • Ideal gas with molar heat capacity: Cˉv=52R\bar C_v = \frac{5}{2}RCˉv​=25​R
  • Adiabatic process: q=0q=0q=0
  • External pressure is constant: Pext=1 atmP_{\text{ext}}=1\,\text{atm}Pext​=1atm
  • Initial state: T1=298 K,P1=5 atmT_1=298\,\text{K},\quad P_1=5\,\text{atm}T1​=298K,P1​=5atm
  • Final volume is double the initial volume: V2=2V1V_2=2V_1V2​=2V1​

We need the final temperature T2T_2T2​.


  1. Apply first law of thermodynamics

For an adiabatic process: ΔU=q+w=w\Delta U = q+w = wΔU=q+w=w

For expansion against constant external pressure: w=−Pext(V2−V1)w=-P_{\text{ext}}(V_2-V_1)w=−Pext​(V2​−V1​)

For an ideal gas: ΔU=nCˉv(T2−T1)\Delta U = n\bar C_v(T_2-T_1)ΔU=nCˉv​(T2​−T1​)

So, nCˉv(T2−T1)=−Pext(V2−V1)n\bar C_v(T_2-T_1)=-P_{\text{ext}}(V_2-V_1)nCˉv​(T2​−T1​)=−Pext​(V2​−V1​)

Since V2=2V1V_2=2V_1V2​=2V1​, V2−V1=V1V_2-V_1=V_1V2​−V1​=V1​

Hence, nCˉv(T2−T1)=−PextV1n\bar C_v(T_2-T_1)=-P_{\text{ext}}V_1nCˉv​(T2​−T1​)=−Pext​V1​


  1. Use ideal gas equation for initial state

Initially, P1V1=nRT1P_1V_1=nRT_1P1​V1​=nRT1​

Thus, V1=nRT1P1V_1=\frac{nRT_1}{P_1}V1​=P1​nRT1​​

Substitute into energy equation: nCˉv(T2−T1)=−Pext(nRT1P1)n\bar C_v(T_2-T_1)=-P_{\text{ext}}\left(\frac{nRT_1}{P_1}\right)nCˉv​(T2​−T1​)=−Pext​(P1​nRT1​​)

Cancel nnn: Cˉv(T2−T1)=−PextP1RT1\bar C_v(T_2-T_1)=-\frac{P_{\text{ext}}}{P_1}RT_1Cˉv​(T2​−T1​)=−P1​Pext​​RT1​

Now substitute Cˉv=52R\bar C_v=\frac{5}{2}RCˉv​=25​R: 52R(T2−T1)=−15RT1\frac{5}{2}R(T_2-T_1)=-\frac{1}{5}RT_125​R(T2​−T1​)=−51​RT1​

Cancel RRR: 52(T2−T1)=−T15\frac{5}{2}(T_2-T_1)=-\frac{T_1}{5}25​(T2​−T1​)=−5T1​​

With T1=298 KT_1=298\,\text{K}T1​=298K: 52(T2−298)=−2985\frac{5}{2}(T_2-298)=-\frac{298}{5}25​(T2​−298)=−5298​

So, T2−298=−2985⋅25=−59625=−23.84T_2-298=-\frac{298}{5}\cdot\frac{2}{5}=-\frac{596}{25}=-23.84T2​−298=−5298​⋅52​=−25596​=−23.84

Therefore, T2=298−23.84=274.16 KT_2=298-23.84=274.16\,\text{K}T2​=298−23.84=274.16K

Nearest integer: 274 K\boxed{274\,\text{K}}274K​


  1. Comparison with stored answer

Stored correct answer = 274

Our derived answer = 274

So the answer agrees.

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