JEE MainChemistryThermodynamicsNumerical+4 / −1
An ideal gas, , is expanded adiabatically against a constant pressure of 1 atm untill it doubles in volume. If the initial temperature and pressure is and , respectively then the final temperature is (nearest integer). [ is the molar heat capacity at constant volume]
Numerical answer
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Correct answer: 274
- Given data
- Ideal gas with molar heat capacity:
- Adiabatic process:
- External pressure is constant:
- Initial state:
- Final volume is double the initial volume:
We need the final temperature .
- Apply first law of thermodynamics
For an adiabatic process:
For expansion against constant external pressure:
For an ideal gas:
So,
Since ,
Hence,
- Use ideal gas equation for initial state
Initially,
Thus,
Substitute into energy equation:
Cancel :
Now substitute :
Cancel :
With :
So,
Therefore,
Nearest integer:
- Comparison with stored answer
Stored correct answer = 274
Our derived answer = 274
So the answer agrees.
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