JEE MainChemistryThermodynamicsNumerical+4 / −1
The average S-F bond energy in kJ mol 1 of is . (Rounded off to the nearest integer) [Given : The values of standard enthalpy of formation of (g), S(g) and F(g) are - 1100, 275 and 80 kJ mol 1 respectively.]
Numerical answer
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Correct answer: 309
- What is meant by average bond energy?
For , the average bond energy is the energy required to break all 6 bonds in 1 mole of gaseous to form gaseous atoms:
If the total atomization enthalpy is , then
- Use enthalpy of formation data
Given:
For the reaction
by Hess's law,
So,
- Find average bond energy
There are 6 identical bonds in , so
Rounded to nearest integer:
- Comparison with stored answer
Stored correct answer =
Our derived answer =
So the answer agrees with the stored correct answer.
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