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Thermodynamics question

2021 · 26 Feb · Shift 2 · Q20
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Thermodynamics question

2021 · 26 Feb · Shift 2 · Q20

JEE MainChemistryThermodynamicsNumerical+4 / −1
The average S-F bond energy in kJ mol −-− 1 of SF6SF_6SF6​ is ‾\underline{\hspace{2cm}}​. (Rounded off to the nearest integer) [Given : The values of standard enthalpy of formation of SF6SF_6SF6​(g), S(g) and F(g) are - 1100, 275 and 80 kJ mol −-− 1 respectively.]
Numerical answer
View written solutionFree

Correct answer: 309

  1. What is meant by average bond energy?

For SF6SF_6SF6​, the average S−FS-FS−F bond energy is the energy required to break all 6 S−FS-FS−F bonds in 1 mole of gaseous SF6SF_6SF6​ to form gaseous atoms:

SF6(g)→S(g)+6F(g)SF_6(g) \rightarrow S(g) + 6F(g)SF6​(g)→S(g)+6F(g)

If the total atomization enthalpy is ΔH\Delta HΔH, then

Average S−F bond energy=ΔH6\text{Average } S-F \text{ bond energy} = \frac{\Delta H}{6}Average S−F bond energy=6ΔH​


  1. Use enthalpy of formation data

Given:

ΔHf∘[SF6(g)]=−1100 kJ mol−1\Delta H_f^\circ[SF_6(g)] = -1100\ \text{kJ mol}^{-1}ΔHf∘​[SF6​(g)]=−1100 kJ mol−1 ΔHf∘[S(g)]=275 kJ mol−1\Delta H_f^\circ[S(g)] = 275\ \text{kJ mol}^{-1}ΔHf∘​[S(g)]=275 kJ mol−1 ΔHf∘[F(g)]=80 kJ mol−1\Delta H_f^\circ[F(g)] = 80\ \text{kJ mol}^{-1}ΔHf∘​[F(g)]=80 kJ mol−1

For the reaction

SF6(g)→S(g)+6F(g)SF_6(g) \rightarrow S(g) + 6F(g)SF6​(g)→S(g)+6F(g)

by Hess's law,

ΔH=∑ΔHf∘(products)−∑ΔHf∘(reactants)\Delta H = \sum \Delta H_f^\circ(\text{products}) - \sum \Delta H_f^\circ(\text{reactants})ΔH=∑ΔHf∘​(products)−∑ΔHf∘​(reactants)

So,

ΔH=[275+6(80)]−[−1100]\Delta H = [275 + 6(80)] - [-1100]ΔH=[275+6(80)]−[−1100]

=275+480+1100= 275 + 480 + 1100=275+480+1100

=1855 kJ mol−1= 1855\ \text{kJ mol}^{-1}=1855 kJ mol−1


  1. Find average bond energy

There are 6 identical S−FS-FS−F bonds in SF6SF_6SF6​, so

Average bond energy=18556\text{Average bond energy} = \frac{1855}{6}Average bond energy=61855​

=309.166… kJ mol−1= 309.166\ldots\ \text{kJ mol}^{-1}=309.166… kJ mol−1

Rounded to nearest integer:

309 kJ mol−1\boxed{309\ \text{kJ mol}^{-1}}309 kJ mol−1​


  1. Comparison with stored answer

Stored correct answer = 309309309

Our derived answer = 309309309

So the answer agrees with the stored correct answer.

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