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Structure of Atom question

2025 · 29 Jan · Shift 2 · Q16
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Structure of Atom question

2025 · 29 Jan · Shift 2 · Q16

JEE MainChemistryStructure of AtomMCQ+4 / −1
Given below are two statements : Statement (I): It is impossible to specify simultaneously with arbitrary precision, both the linear momentum and the position of a particle. Statement (II) : If the uncertainty in the measurement of position and uncertainty in measurement of momentum are equal for an electron, then the uncertainty in the measurement of velocity is ⩾hπ×12m\geqslant \sqrt{\frac{h}{\pi}} \times \frac{1}{2 m}⩾πh​​×2m1​. In the light of the above statements, choose the correct answer from the options given below :
  1. A
    Statement I is false but Statement II is true
  2. B
    Both Statement I and Statement II are true
  3. C
    Both Statement I and Statement II are false
  4. D
    Statement I is true but Statement II is false
View written solutionFree

Correct answer: B

  1. Check Statement (I)

Statement (I) says:

It is impossible to specify simultaneously with arbitrary precision, both the linear momentum and the position of a particle.

This is exactly Heisenberg's uncertainty principle:

Δx Δp≥h4π\Delta x \, \Delta p \geq \frac{h}{4\pi}ΔxΔp≥4πh​

So, position and momentum cannot both be measured exactly at the same time.

Therefore, Statement (I) is true.


  1. Check Statement (II)

Given:

  • uncertainty in position = uncertainty in momentum
  • for an electron, find uncertainty in velocity

Let

Δx=Δp\Delta x = \Delta pΔx=Δp

Using Heisenberg's uncertainty principle:

Δx Δp≥h4π\Delta x\,\Delta p \geq \frac{h}{4\pi}ΔxΔp≥4πh​

Since Δx=Δp\Delta x = \Delta pΔx=Δp,

(Δp)2≥h4π(\Delta p)^2 \geq \frac{h}{4\pi}(Δp)2≥4πh​

Taking square root,

Δp≥h4π=12hπ\Delta p \geq \sqrt{\frac{h}{4\pi}} = \frac{1}{2}\sqrt{\frac{h}{\pi}}Δp≥4πh​​=21​πh​​

Now for an electron,

Δp=m Δv\Delta p = m\,\Delta vΔp=mΔv

So,

m Δv≥12hπm\,\Delta v \geq \frac{1}{2}\sqrt{\frac{h}{\pi}}mΔv≥21​πh​​

Hence,

Δv≥hπ×12m\Delta v \geq \sqrt{\frac{h}{\pi}}\times \frac{1}{2m}Δv≥πh​​×2m1​

This matches Statement (II).

Therefore, Statement (II) is also true.


  1. Conclusion
  • Statement (I): True
  • Statement (II): True

So the correct option is:

B\boxed{\text{B}}B​
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