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Structure of Atom question

2024 · 4 Apr · Shift 1 · Q27
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Structure of Atom question

2024 · 4 Apr · Shift 1 · Q27

JEE MainChemistryStructure of AtomNumerical+4 / −1
The de-Broglie's wavelength of an electron in the 4th 4^{\text {th }}4th  orbit is ‾\underline{\hspace{2cm}}​πa0\pi \mathrm{a}_0πa0​. (a0=\mathrm{a}_0=a0​= Bohr's radius)
Numerical answer
View written solutionFree

Correct answer: 8

  1. Use Bohr’s quantization condition

    For an electron in the nthn^{\text{th}}nth Bohr orbit, 2πrn=nλ2\pi r_n = n\lambda2πrn​=nλ where λ\lambdaλ is the de-Broglie wavelength.

  2. Radius of the nthn^{\text{th}}nth orbit

    In Bohr model, rn=n2a0r_n = n^2 a_0rn​=n2a0​

    For the 4th4^{\text{th}}4th orbit: r4=42a0=16a0r_4 = 4^2 a_0 = 16a_0r4​=42a0​=16a0​

  3. Apply the standing wave condition

    2πr4=4λ2\pi r_4 = 4\lambda2πr4​=4λ

    Substituting r4=16a0r_4 = 16a_0r4​=16a0​: 2π(16a0)=4λ2\pi(16a_0) = 4\lambda2π(16a0​)=4λ 32πa0=4λ32\pi a_0 = 4\lambda32πa0​=4λ λ=8πa0\lambda = 8\pi a_0λ=8πa0​

  4. Compare with the required form

    The question asks: λ=‾ πa0\lambda = \underline{\hspace{2cm}}\,\pi a_0λ=​πa0​

    Hence the blank is: 888

Final Answer: 888

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