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Structure of Atom question

2023 · 30 Jan · Shift 1 · Q22
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Structure of Atom question

2023 · 30 Jan · Shift 1 · Q22

JEE MainChemistryStructure of AtomNumerical+4 / −1
The energy of one mole of photons of radiation of frequency 2×1012 Hz2 \times 10^{12} \mathrm{~Hz}2×1012 Hz in J mol−1\mathrm{J} ~\mathrm{mol}^{-1}J mol−1 is ‾\underline{\hspace{2cm}}​. (Nearest integer) [Given : h=6.626×10−34 Js\mathrm{h}=6.626 \times 10^{-34} ~\mathrm{Js}h=6.626×10−34 Js NA=6.022×1023 mol−1\mathrm{N}_{\mathrm{A}}=6.022 \times 10^{23} \mathrm{~mol}^{-1}NA​=6.022×1023 mol−1]
Numerical answer
View written solutionFree

Correct answer: 798

  1. Energy of one photon

The energy of a photon is given by:

E=hνE = h\nuE=hν

Given:

h=6.626×10−34 J sh = 6.626 \times 10^{-34}\ \text{J s}h=6.626×10−34 J s ν=2×1012 Hz\nu = 2 \times 10^{12}\ \text{Hz}ν=2×1012 Hz

So,

E=(6.626×10−34)(2×1012)E = (6.626 \times 10^{-34})(2 \times 10^{12})E=(6.626×10−34)(2×1012)

E=13.252×10−22 JE = 13.252 \times 10^{-22}\ \text{J}E=13.252×10−22 J

E=1.3252×10−21 J per photonE = 1.3252 \times 10^{-21}\ \text{J per photon}E=1.3252×10−21 J per photon

  1. Energy of one mole of photons

One mole contains Avogadro's number of photons:

NA=6.022×1023 mol−1N_A = 6.022 \times 10^{23}\ \text{mol}^{-1}NA​=6.022×1023 mol−1

Therefore,

Emol=E×NAE_{\text{mol}} = E \times N_AEmol​=E×NA​

Emol=(1.3252×10−21)(6.022×1023)E_{\text{mol}} = (1.3252 \times 10^{-21})(6.022 \times 10^{23})Emol​=(1.3252×10−21)(6.022×1023)

Now multiply the coefficients:

1.3252×6.022=7.98075441.3252 \times 6.022 = 7.98075441.3252×6.022=7.9807544

And combine powers of 10:

10−21×1023=10210^{-21} \times 10^{23} = 10^210−21×1023=102

Thus,

Emol=7.9807544×102 J mol−1E_{\text{mol}} = 7.9807544 \times 10^2\ \text{J mol}^{-1}Emol​=7.9807544×102 J mol−1

Emol=798.07544 J mol−1E_{\text{mol}} = 798.07544\ \text{J mol}^{-1}Emol​=798.07544 J mol−1

  1. Nearest integer

Emol≈798 J mol−1E_{\text{mol}} \approx 798\ \text{J mol}^{-1}Emol​≈798 J mol−1

Final Answer

798\boxed{798}798​

The derived answer matches the stored correct answer.

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