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Structure of Atom question

2021 · 27 Aug · Shift 1 · Q15
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Structure of Atom question

2021 · 27 Aug · Shift 1 · Q15

JEE MainChemistryStructure of AtomNumerical+4 / −1
The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is equal to h2xma02{{{h^2}} \over {xma_0^2}}xma02​h2​. The value of 10x is ‾\underline{\hspace{2cm}}​. (a0 is radius of Bohr's orbit) (Nearest integer) [Given : π\piπ = 3.14]
Numerical answer
View written solutionFree

Correct answer: 3155

  1. Use Bohr model relations

For the hydrogen atom:

  • Radius of the nnnth Bohr orbit: rn=n2a0r_n = n^2 a_0rn​=n2a0​
  • Angular momentum quantization: mvrn=nh2πmvr_n = \frac{nh}{2\pi}mvrn​=2πnh​

For the second orbit, n=2n=2n=2, so r2=4a0r_2 = 4a_0r2​=4a0​

  1. Expression for kinetic energy

Kinetic energy of the electron is K=12mv2K = \frac{1}{2}mv^2K=21​mv2

From Bohr's quantization, v=nh2πmrnv = \frac{nh}{2\pi m r_n}v=2πmrn​nh​

So,

= \frac{n^2h^2}{8\pi^2 m r_n^2}$$ Now substitute $r_n = n^2a_0$: $$K = \frac{n^2h^2}{8\pi^2 m (n^2a_0)^2} = \frac{h^2}{8\pi^2 m n^2 a_0^2}$$ For $n=2$: $$K = \frac{h^2}{8\pi^2 m (4)a_0^2} = \frac{h^2}{32\pi^2 m a_0^2}$$ 3. **Compare with the given form** Given: $$K = \frac{h^2}{xma_0^2}$$ Hence, $$x = 32\pi^2$$ 4. **Calculate $10x$** Using $\pi = 3.14$, $$x = 32(3.14)^2$$ $$x = 32(9.8596) = 315.5072$$ Therefore, $$10x = 3155.072$$ Nearest integer: $$\boxed{3155}$$ 5. **Comparison with stored answer** Derived answer = $3155$ Stored correct answer = $3155$ They match.
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