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Structure of Atom question

2021 · 31 Aug · Shift 1 · Q20
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Structure of Atom question

2021 · 31 Aug · Shift 1 · Q20

JEE MainChemistryStructure of AtomNumerical+4 / −1
Ge(Z = 32) in its ground state electronic configuration has x completely filled orbitals with ml = 0. The value of x is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 7

  1. Write the ground state electronic configuration of Ge (Z=32Z=32Z=32):
Ge:1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p2\text{Ge}: 1s^2\,2s^2\,2p^6\,3s^2\,3p^6\,3d^{10}\,4s^2\,4p^2Ge:1s22s22p63s23p63d104s24p2
  1. Find orbitals with ml=0m_l=0ml​=0 in each subshell and count only those that are completely filled.

For a subshell with azimuthal quantum number lll, the possible values of mlm_lml​ are:

ml=−l,−(l−1),…,0,…,+(l−1),+lm_l = -l, -(l-1), \dots, 0, \dots, +(l-1), +lml​=−l,−(l−1),…,0,…,+(l−1),+l

So each subshell has exactly one orbital with ml=0m_l=0ml​=0.

Now check each occupied subshell:

  • 1s21s^21s2: for sss, l=0l=0l=0, so only ml=0m_l=0ml​=0 exists. This orbital is completely filled. Count = 1
  • 2s22s^22s2: completely filled ml=0m_l=0ml​=0 orbital. Count = 1
  • 2p62p^62p6: ppp has ml=−1,0,+1m_l=-1,0,+1ml​=−1,0,+1; the ml=0m_l=0ml​=0 orbital is filled in p6p^6p6. Count = 1
  • 3s23s^23s2: completely filled ml=0m_l=0ml​=0 orbital. Count = 1
  • 3p63p^63p6: ml=0m_l=0ml​=0 orbital completely filled. Count = 1
  • 3d103d^{10}3d10: ddd has ml=−2,−1,0,+1,+2m_l=-2,-1,0,+1,+2ml​=−2,−1,0,+1,+2; in d10d^{10}d10 all are completely filled, so the ml=0m_l=0ml​=0 orbital is completely filled. Count = 1
  • 4s24s^24s2: completely filled ml=0m_l=0ml​=0 orbital. Count = 1
  • 4p24p^24p2: here ppp subshell is not completely filled. By Hund’s rule, the two electrons occupy two different ppp orbitals singly, so the ml=0m_l=0ml​=0 orbital is not certainly completely filled. Hence do not count it.
  1. Total count:
x=1+1+1+1+1+1+1=7x = 1+1+1+1+1+1+1 = 7x=1+1+1+1+1+1+1=7
  1. Final answer:
7\boxed{7}7​
  1. Comparison with stored correct answer:

Stored correct answer = 7, which matches the derived answer.

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