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Structure of Atom question

2021 · 25 Jul · Shift 1 · Q17
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Structure of Atom question

2021 · 25 Jul · Shift 1 · Q17

JEE MainChemistryStructure of AtomNumerical+4 / −1
A source of monochromatic radiation of wavelength 400 nm provides 1000 J of energy in 10 seconds. When this radiation falls on the surface of sodium, x ×\times× 1020 electrons are ejected per second. Assume that wavelength 400 nm is sufficient for ejection of electron from the surface of sodium metal. The value of x is ‾\underline{\hspace{2cm}}​. (Nearest integer) (h = 6.626 ×\times× 10 −-− 34 Js)
Numerical answer
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Correct answer: 2

  1. Energy supplied per second

The source gives 1000 J1000\,\text{J}1000J in 10 s10\,\text{s}10s.

So, power of the source is

P=100010=100 J s−1P = \frac{1000}{10} = 100\,\text{J s}^{-1}P=101000​=100J s−1

Thus, energy incident per second is 100 J100\,\text{J}100J.

  1. Energy of one photon

Given wavelength,

λ=400 nm=400×10−9 m\lambda = 400\,\text{nm} = 400 \times 10^{-9}\,\text{m}λ=400nm=400×10−9m

Energy of one photon is

E=hcλE = \frac{hc}{\lambda}E=λhc​

Substitute values:

E=(6.626×10−34)(3×108)400×10−9E = \frac{(6.626 \times 10^{-34})(3 \times 10^8)}{400 \times 10^{-9}}E=400×10−9(6.626×10−34)(3×108)​ E=19.878×10−264×10−7E = \frac{19.878 \times 10^{-26}}{4 \times 10^{-7}}E=4×10−719.878×10−26​ E=4.97×10−19 JE = 4.97 \times 10^{-19}\,\text{J}E=4.97×10−19J
  1. Number of photons incident per second

If all the supplied energy is in this monochromatic radiation, then

photons per second=1004.97×10−19\text{photons per second} = \frac{100}{4.97 \times 10^{-19}}photons per second=4.97×10−19100​ =2.01×1020= 2.01 \times 10^{20}=2.01×1020
  1. Number of electrons ejected per second

Since the wavelength is sufficient for photoelectric emission, and one photon can eject at most one electron,

electrons ejected per second=2.01×1020\text{electrons ejected per second} = 2.01 \times 10^{20}electrons ejected per second=2.01×1020

Given this is written as x×1020x \times 10^{20}x×1020, we get

x≈2x \approx 2x≈2
  1. Nearest integer
x=2\boxed{x = 2}x=2​
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