Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Structure of Atom question

2021 · 24 Feb · Shift 1 · Q16
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Structure of Atom
  5. /2021 · 24 Feb · Shift 1 · Q16

Structure of Atom question

2021 · 24 Feb · Shift 1 · Q16

JEE MainChemistryStructure of AtomNumerical+4 / −1
A proton and a Li3+Li^{3+}Li3+ nucleus are accelerated by the same potential. If λLi\lambda _{Li}λLi​ and λp\lambda _pλp​ denote the de Broglie wavelengths of Li3+Li^{3+}Li3+ and proton respectively, then the value of λLiλp{{{\lambda _{Li}}} \over {{\lambda _p}}}λp​λLi​​ is x ×\times× 10-1. The value of x is ‾\underline{\hspace{2cm}}​. (Rounded off to the nearest integer) [Mass of Li3+Li^{3+}Li3+ = 8.3 mass of proton]
Numerical answer
View written solutionFree

Correct answer: 2

  1. Use de Broglie wavelength formula

For a particle,

λ=hp\lambda = \frac{h}{p}λ=ph​

where ppp is momentum.

If a charged particle is accelerated through a potential difference VVV, then its kinetic energy is

qV=p22mqV = \frac{p^2}{2m}qV=2mp2​

So,

p=2mqVp = \sqrt{2mqV}p=2mqV​

Hence,

λ=h2mqV\lambda = \frac{h}{\sqrt{2mqV}}λ=2mqV​h​

Thus,

λ∝1mq\lambda \propto \frac{1}{\sqrt{mq}}λ∝mq​1​

for the same accelerating potential VVV.


  1. Apply to proton and Li3+Li^{3+}Li3+ nucleus

For proton:

  • mass =mp= m_p=mp​
  • charge =e= e=e

For Li3+Li^{3+}Li3+ nucleus:

  • mass =8.3 mp= 8.3\,m_p=8.3mp​
  • charge =3e= 3e=3e

Therefore,

λLiλp=mp e(8.3mp)(3e)\frac{\lambda_{Li}}{\lambda_p} = \sqrt{\frac{m_p\,e}{(8.3m_p)(3e)}}λp​λLi​​=(8.3mp​)(3e)mp​e​​

Cancel mpm_pmp​ and eee:

λLiλp=18.3×3\frac{\lambda_{Li}}{\lambda_p} = \frac{1}{\sqrt{8.3\times 3}}λp​λLi​​=8.3×3​1​ 8.3×3=24.98.3 \times 3 = 24.98.3×3=24.9

So,

λLiλp=124.9\frac{\lambda_{Li}}{\lambda_p} = \frac{1}{\sqrt{24.9}}λp​λLi​​=24.9​1​

Now,

24.9≈4.99\sqrt{24.9} \approx 4.9924.9​≈4.99

Thus,

λLiλp≈14.99≈0.200\frac{\lambda_{Li}}{\lambda_p} \approx \frac{1}{4.99} \approx 0.200λp​λLi​​≈4.991​≈0.200
  1. Match with given form

Given,

λLiλp=x×10−1\frac{\lambda_{Li}}{\lambda_p} = x \times 10^{-1}λp​λLi​​=x×10−1

Since,

0.200=2.00×10−10.200 = 2.00 \times 10^{-1}0.200=2.00×10−1

So,

x=2x = 2x=2
  1. Comparison with stored answer

Derived answer: 222

Stored correct answer: 222

Both match.

PreviousNext

More from Structure of Atom

  • According to Bohr's atomic theory : (A) Kinetic energy of electron is ∝n2Z2​. (B) The product of velocity (v) of electron and principal quantum number (n), ′vn′∝Z2. (C) Frequency of revolution of…2021 · MCQ
  • The plots of radial distribution functions for various orbitals of hydrogen atom against 'r' are given below : The correct plot for 3s orbital is : Includes diagram2021 · MCQ
  • Electromagnetic radiation of wavelength 663 nm is just sufficient to ionise the atom of metal A. The ionization enegy of metal A in kJ mol − 1 is ​. (Rounded off to the nearest integer) [h = 6.63 × 10 −…2021 · Numerical
  • Among the following, number of metal/s which can be used as electrodes in the photoelectric cell is ​. (Integer answer) (A) Li (B) Na (C) Rb (D) Cs2021 · Numerical
  • A source of monochromatic radiation of wavelength 400 nm provides 1000 J of energy in 10 seconds. When this radiation falls on the surface of sodium, x × 1020 electrons are ejected per second. Assume that wavelength 400 nm is…2021 · Numerical
  • An accelerated electron has a speed of 5 × 106 ms − 1 with an uncertainty of 0.02%. The uncertainty in finding its location while in motion is x × 10 − 9 m. The value of x is ​. (Nearest integer)…2021 · Numerical
  • Given below are two statements. Statement I : According to Bohr's model of an atom, qualitatively the magnitude of velocity of electron increases with decrease in positive charges on the nucleus as there is no strong hold on the electron…2021 · MCQ
  • A metal surface is exposed to 500 nm radiation. The threshold frequency of the metal for photoelectric current is 4.3 × 1014 Hz. The velocity of ejected electron is ​× 105 ms − 1 (Nearest integer)…2021 · Numerical