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Structure of Atom question

2021 · 25 Feb · Shift 1 · Q3
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Structure of Atom question

2021 · 25 Feb · Shift 1 · Q3

JEE MainChemistryStructure of AtomMCQ+4 / −1
The plots of radial distribution functions for various orbitals of hydrogen atom against 'r' are given below : JEE Main 2021 (Online) 25th February Morning Shift Chemistry - Structure of Atom Question 123 English The correct plot for 3s orbital is :
  1. A
    (B)
  2. B
    (A)
  3. C
    (C)
  4. D
    (D)
View written solutionFree

Correct answer: D

  1. What is being asked?

We need to identify the correct radial distribution plot for the 3s3s3s orbital of the hydrogen atom.

The radial distribution function is: P(r)=4πr2∣R(r)∣2P(r)=4\pi r^2 |R(r)|^2P(r)=4πr2∣R(r)∣2 It gives the probability of finding the electron between rrr and r+drr+drr+dr.


  1. Key facts for hydrogenic orbitals

For an orbital with quantum numbers nnn and lll:

  • Number of radial nodes =n−l−1= n-l-1=n−l−1
  • Near r=0r=0r=0, the behavior depends on lll
  • For an sss-orbital, l=0l=0l=0

For 3s3s3s orbital: n=3,l=0n=3,\quad l=0n=3,l=0 So number of radial nodes is: 3−0−1=23-0-1=23−0−1=2

Thus the radial distribution curve for 3s3s3s must have:

  • starts from zero at r=0r=0r=0 (because of the r2r^2r2 factor in P(r)P(r)P(r)),
  • three maxima,
  • two radial nodes in between.

  1. How do sss, ppp, ddd curves differ?

For the orbitals in the same shell n=3n=3n=3:

  • 3s3s3s: 222 radial nodes
  • 3p3p3p: 111 radial node
  • 3d3d3d: 000 radial nodes

Therefore among the given plots, the correct one for 3s3s3s must be the one with the largest number of peaks/intersections with the axis among the n=3n=3n=3 orbitals.


  1. Matching with the given plots

Since the options are written as:

  • A: (B)(B)(B)
  • B: (A)(A)(A)
  • C: (C)(C)(C)
  • D: (D)(D)(D)

we must choose the figure labeled with the graph that shows two radial nodes and three peaks. That corresponds to plot (D).

Hence the correct option is: D\boxed{\text{D}}D​


  1. Verification with stored answer

Stored correct answer: D

Our derived answer: D

So they agree.

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