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Structure of Atom question

2021 · 20 Jul · Shift 1 · Q14
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Structure of Atom question

2021 · 20 Jul · Shift 1 · Q14

JEE MainChemistryStructure of AtomNumerical+4 / −1
The Azimuthal quantum number for the valence electrons of Ga+Ga^+Ga+ ion is ‾\underline{\hspace{2cm}}​. (Atomic number of Ga = 31)
Numerical answer
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Correct answer: 0

  1. Write the electronic configuration of Ga

Gallium has atomic number 313131.

So, the electronic configuration of Ga\mathrm{Ga}Ga is:

Ga:[Ar] 3d104s24p1\mathrm{Ga}: [Ar] \, 3d^{10} 4s^2 4p^1Ga:[Ar]3d104s24p1
  1. Find the configuration of Ga+\mathrm{Ga}^+Ga+

To form Ga+\mathrm{Ga}^+Ga+, one electron is removed from the outermost shell.

The outermost electron is the 4p14p^14p1 electron, so:

Ga+:[Ar] 3d104s2\mathrm{Ga}^+: [Ar] \, 3d^{10} 4s^2Ga+:[Ar]3d104s2
  1. Identify the valence electrons

Valence electrons are the electrons in the outermost shell, i.e. the shell with highest principal quantum number nnn.

For Ga+\mathrm{Ga}^+Ga+, the highest value of nnn is 444, and the electrons present there are:

4s24s^24s2

So, the valence electrons are in the sss-subshell.

  1. Azimuthal quantum number for an sss-subshell

The azimuthal quantum number lll is:

  • s→l=0s \rightarrow l=0s→l=0
  • p→l=1p \rightarrow l=1p→l=1
  • d→l=2d \rightarrow l=2d→l=2
  • f→l=3f \rightarrow l=3f→l=3

Since the valence electrons are in the 4s4s4s subshell,

l=0l = 0l=0
  1. Final answer

The azimuthal quantum number for the valence electrons of Ga+\mathrm{Ga}^+Ga+ is:

0\boxed{0}0​
  1. Comparison with stored correct answer

Stored correct answer = 000.

This matches the derived answer.

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