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Some Basic Concepts of Chemistry question

2022 · 29 Jul · Shift 1 · Q2
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  5. /2022 · 29 Jul · Shift 1 · Q2

Some Basic Concepts of Chemistry question

2022 · 29 Jul · Shift 1 · Q2

JEE MainChemistrySome Basic Concepts of ChemistryMCQ+4 / −1
N2( g)+3H2( g)⇌2NH3( g)\mathrm{N}_{2(\mathrm{~g})}+3 \mathrm{H}_{2(\mathrm{~g})} \rightleftharpoons 2 \mathrm{NH}_{3(\mathrm{~g})}N2( g)​+3H2( g)​⇌2NH3( g)​ 20 g   5 g20 \mathrm{~g} \quad ~~~5 \mathrm{~g}20 g   5 g Consider the above reaction, the limiting reagent of the reaction and number of moles of NH3\mathrm{NH}_{3}NH3​ formed respectively are :
  1. A
    H2,1.42\mathrm{H}_{2}, 1.42H2​,1.42 moles
  2. B
    H2,0.71\mathrm{H}_{2}, 0.71H2​,0.71 moles
  3. C
    N2,1.42\mathrm{N}_{2}, 1.42N2​,1.42 moles
  4. D
    N2,0.71\mathrm{N}_{2}, 0.71N2​,0.71 moles
View written solutionFree

Correct answer: C

  1. Write the balanced reaction

N2(g)+3H2(g)→2NH3(g)\mathrm{N_2(g)} + 3\mathrm{H_2(g)} \rightarrow 2\mathrm{NH_3(g)}N2​(g)+3H2​(g)→2NH3​(g)

Given masses:

  • N2=20 g\mathrm{N_2} = 20\,\text{g}N2​=20g
  • H2=5 g\mathrm{H_2} = 5\,\text{g}H2​=5g
  1. Calculate moles of reactants

For nitrogen: n(N2)=2028=0.714 moln(\mathrm{N_2}) = \frac{20}{28} = 0.714\,\text{mol}n(N2​)=2820​=0.714mol

For hydrogen: n(H2)=52=2.5 moln(\mathrm{H_2}) = \frac{5}{2} = 2.5\,\text{mol}n(H2​)=25​=2.5mol

  1. Find the limiting reagent

From the balanced equation: 1 mol N2 requires 3 mol H21\,\text{mol } \mathrm{N_2} \text{ requires } 3\,\text{mol } \mathrm{H_2}1mol N2​ requires 3mol H2​

So, 0.7140.7140.714 mol N2\mathrm{N_2}N2​ requires: 0.714×3=2.142 mol H20.714 \times 3 = 2.142\,\text{mol } \mathrm{H_2}0.714×3=2.142mol H2​

Available H2=2.5\mathrm{H_2} = 2.5H2​=2.5 mol, which is more than required.

Therefore, N2\mathrm{N_2}N2​ is the limiting reagent.

  1. Calculate moles of ammonia formed

From the reaction: 1 mol N2→2 mol NH31\,\text{mol } \mathrm{N_2} \rightarrow 2\,\text{mol } \mathrm{NH_3}1mol N2​→2mol NH3​

Thus, 0.714 mol N2→0.714×2=1.428 mol NH30.714\,\text{mol } \mathrm{N_2} \rightarrow 0.714 \times 2 = 1.428\,\text{mol } \mathrm{NH_3}0.714mol N2​→0.714×2=1.428mol NH3​

So, moles of ammonia formed ≈1.42\approx 1.42≈1.42 mol.

  1. Match with options
  • Limiting reagent = N2\mathrm{N_2}N2​
  • Moles of NH3\mathrm{NH_3}NH3​ formed = 1.421.421.42

Hence, the correct option is:

C\boxed{\text{C}}C​

  1. Comparison with stored answer

Stored correct answer: C

My derived answer: C

They agree.

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