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Some Basic Concepts of Chemistry question

2022 · 28 Jun · Shift 2 · Q19
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Some Basic Concepts of Chemistry question

2022 · 28 Jun · Shift 2 · Q19

JEE MainChemistrySome Basic Concepts of ChemistryNumerical+4 / −1
The complete combustion of 0.492 g of an organic compound containing 'C', 'H' and 'O' gives 0.793 g of CO2CO_2CO2​ and 0.442 g of H2OH_2OH2​O. The percentage of oxygen composition in the organic compound is ‾\underline{\hspace{2cm}}​. (nearest integer)
Numerical answer
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Correct answer: 46

  1. Given data
  • Mass of organic compound =0.492 g= 0.492\,\text{g}=0.492g
  • On complete combustion:
    • Mass of CO2=0.793 gCO_2 = 0.793\,\text{g}CO2​=0.793g
    • Mass of H2O=0.442 gH_2O = 0.442\,\text{g}H2​O=0.442g

The compound contains only CCC, HHH, and OOO.


  1. Mass of carbon in the compound

All carbon in the compound goes to CO2CO_2CO2​.

Mass of C=0.793×1244\text{Mass of C} = 0.793 \times \frac{12}{44}Mass of C=0.793×4412​

Mass of C=0.21627 g\text{Mass of C} = 0.21627\,\text{g}Mass of C=0.21627g


  1. Mass of hydrogen in the compound

All hydrogen in the compound goes to H2OH_2OH2​O.

Mass of H=0.442×218\text{Mass of H} = 0.442 \times \frac{2}{18}Mass of H=0.442×182​

Mass of H=0.04911 g\text{Mass of H} = 0.04911\,\text{g}Mass of H=0.04911g


  1. Mass of oxygen in the compound

Since the compound contains only CCC, HHH, and OOO,

Mass of O=Mass of compound−(Mass of C+Mass of H)\text{Mass of O} = \text{Mass of compound} - (\text{Mass of C} + \text{Mass of H})Mass of O=Mass of compound−(Mass of C+Mass of H)

Mass of O=0.492−(0.21627+0.04911)\text{Mass of O} = 0.492 - (0.21627 + 0.04911)Mass of O=0.492−(0.21627+0.04911)

Mass of O=0.22662 g\text{Mass of O} = 0.22662\,\text{g}Mass of O=0.22662g


  1. Percentage of oxygen

% O=0.226620.492×100\%\,O = \frac{0.22662}{0.492} \times 100%O=0.4920.22662​×100

% O=46.06%\%\,O = 46.06\%%O=46.06%

Nearest integer:

46\boxed{46}46​


  1. Comparison with stored answer

Stored correct answer =46= 46=46

Our derived answer =46= 46=46

So, the answer agrees with the stored correct answer.

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