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Some Basic Concepts of Chemistry question

2021 · 18 Mar · Shift 1 · Q19
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Some Basic Concepts of Chemistry question

2021 · 18 Mar · Shift 1 · Q19

JEE MainChemistrySome Basic Concepts of ChemistryNumerical+4 / −1
‾\underline{\hspace{2cm}}​ grams of 3-Hydroxy propanal (MW = 74) must be dehydrated to produce 7.8 g of acrolein (MW = 56) (C3H4OC_3H_4OC3​H4​O) if the percentage yield is 64. (Round off to the Nearest Integer). [Given : Atomic masses : C : 12.0 u, H : 1.0 u, O : 16.0 u ]
Numerical answer
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Correct answer: 16

  1. Write the reaction relation

3-Hydroxy propanal undergoes dehydration to form acrolein:

3-Hydroxy propanal→Acrolein+H2O\text{3-Hydroxy propanal} \rightarrow \text{Acrolein} + H_2O3-Hydroxy propanal→Acrolein+H2​O

So, the mole ratio is:

1:11 : 11:1

That means 1 mole of 3-hydroxy propanal gives 1 mole of acrolein.


  1. Use percentage yield

Given actual mass of acrolein obtained = 7.8 g7.8\,\text{g}7.8g

Percentage yield = 64%64\%64%

So,

Actual yield=64100×Theoretical yield\text{Actual yield} = \frac{64}{100} \times \text{Theoretical yield}Actual yield=10064​×Theoretical yield

Hence theoretical yield of acrolein is:

Theoretical yield=7.8×10064=12.1875 g\text{Theoretical yield} = \frac{7.8 \times 100}{64} = 12.1875\,\text{g}Theoretical yield=647.8×100​=12.1875g


  1. Convert theoretical acrolein mass to moles

Molar mass of acrolein = 565656

n(acrolein)=12.187556=0.21763 moln(\text{acrolein}) = \frac{12.1875}{56} = 0.21763\,\text{mol}n(acrolein)=5612.1875​=0.21763mol

Because of 1:11:11:1 mole ratio,

n(3-hydroxy propanal)=0.21763 moln(\text{3-hydroxy propanal}) = 0.21763\,\text{mol}n(3-hydroxy propanal)=0.21763mol


  1. Find required mass of 3-hydroxy propanal

Molar mass of 3-hydroxy propanal = 747474

m=n×M=0.21763×74=16.104 gm = n \times M = 0.21763 \times 74 = 16.104\,\text{g}m=n×M=0.21763×74=16.104g


  1. Round to nearest integer

16.104≈16 g16.104 \approx 16\,\text{g}16.104≈16g


  1. Final Answer

Required mass of 3-hydroxy propanal is:

16\boxed{16}16​

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