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Solutions question

2023 · 13 Apr · Shift 1 · Q19
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Solutions question

2023 · 13 Apr · Shift 1 · Q19

JEE MainChemistrySolutionsNumerical+4 / −1
Solution of 12 g12 \mathrm{~g}12 g of non-electrolyte (A) prepared by dissolving it in 1000 mL1000 \mathrm{~mL}1000 mL of water exerts the same osmotic pressure as that of 0.05 M0.05 ~\mathrm{M}0.05 M glucose solution at the same temperature. The empirical formula of A\mathrm{A}A is CH2O\mathrm{CH}_{2} \mathrm{O}CH2​O. The molecular mass of A\mathrm{A}A is ‾\underline{\hspace{2cm}}​ g. (Nearest integer)
Numerical answer
View written solutionFree

Correct answer: 240

  1. Use osmotic pressure relation

For a non-electrolyte, π=CRT\pi = C R Tπ=CRT where CCC is molarity.

Since both solutions have the same osmotic pressure at the same temperature, their molar concentrations must be equal.

So, molarity of solution of AAA is: CA=0.05 MC_A = 0.05\,\text{M}CA​=0.05M

  1. Find moles of AAA in the given solution

Volume of solution is approximately 1000 mL=1 L1000\,\text{mL} = 1\,\text{L}1000mL=1L.

Thus moles of AAA in 1 L1\,\text{L}1L solution are: nA=0.05×1=0.05 moln_A = 0.05\times 1 = 0.05\,\text{mol}nA​=0.05×1=0.05mol

  1. Calculate molar mass of AAA

Given mass of A=12 gA = 12\,\text{g}A=12g.

MA=massmoles=120.05=240 g mol−1M_A = \frac{\text{mass}}{\text{moles}} = \frac{12}{0.05} = 240\,\text{g mol}^{-1}MA​=molesmass​=0.0512​=240g mol−1

  1. Check with empirical formula

Empirical formula of AAA is CH2O\mathrm{CH_2O}CH2​O.

Empirical formula mass: 12+2+16=3012 + 2 + 16 = 3012+2+16=30

Molecular mass obtained is: 240=30×8240 = 30 \times 8240=30×8

So molecular formula would be: (CH2O)8=C8H16O8\left(\mathrm{CH_2O}\right)_8 = \mathrm{C_8H_{16}O_8}(CH2​O)8​=C8​H16​O8​

This is consistent.

  1. Final Answer

The molecular mass of AAA is: 240 g\boxed{240\,\text{g}}240g​

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