JEE MainChemistrySolutionsNumerical+4 / −1
Solution of of non-electrolyte (A) prepared by dissolving it in of water exerts the same osmotic pressure as that of glucose solution at the same temperature. The empirical formula of is . The molecular mass of is g. (Nearest integer)
Numerical answer
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Correct answer: 240
- Use osmotic pressure relation
For a non-electrolyte, where is molarity.
Since both solutions have the same osmotic pressure at the same temperature, their molar concentrations must be equal.
So, molarity of solution of is:
- Find moles of in the given solution
Volume of solution is approximately .
Thus moles of in solution are:
- Calculate molar mass of
Given mass of .
- Check with empirical formula
Empirical formula of is .
Empirical formula mass:
Molecular mass obtained is:
So molecular formula would be:
This is consistent.
- Final Answer
The molecular mass of is:
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