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Solutions question

2021 · 20 Jul · Shift 1 · Q21
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Solutions question

2021 · 20 Jul · Shift 1 · Q21

JEE MainChemistrySolutionsNumerical+4 / −1
At 20 ∘^\circ∘ C, the vapour pressure of benzene is 70 torr and that of methyl benzene is 20 torr. The mole fraction of benzene in the vapour phase at 20 ∘^\circ∘ above an equimolar mixture of benzene and methyl benzene is ‾\underline{\hspace{2cm}}​×\times× 10 −-− 2. (Nearest integer)
Numerical answer
View written solutionFree

Correct answer: 78

  1. Use Raoult’s law for an ideal equimolar solution

For an equimolar mixture, xbenzene=xtoluene=12x_{\text{benzene}}=x_{\text{toluene}}=\frac{1}{2}xbenzene​=xtoluene​=21​

Given vapour pressures at 20∘20^\circ20∘C:

  • Benzene: Pbenzene0=70 torrP_{\text{benzene}}^0=70\ \text{torr}Pbenzene0​=70 torr
  • Methyl benzene (toluene): Ptoluene0=20 torrP_{\text{toluene}}^0=20\ \text{torr}Ptoluene0​=20 torr

So partial pressures are: pbenzene=xbenzenePbenzene0=12×70=35 torrp_{\text{benzene}}=x_{\text{benzene}}P_{\text{benzene}}^0=\frac{1}{2}\times 70=35\ \text{torr}pbenzene​=xbenzene​Pbenzene0​=21​×70=35 torr ptoluene=xtoluenePtoluene0=12×20=10 torrp_{\text{toluene}}=x_{\text{toluene}}P_{\text{toluene}}^0=\frac{1}{2}\times 20=10\ \text{torr}ptoluene​=xtoluene​Ptoluene0​=21​×20=10 torr

  1. Find total vapour pressure

Ptotal=35+10=45 torrP_{\text{total}}=35+10=45\ \text{torr}Ptotal​=35+10=45 torr

  1. Find mole fraction of benzene in vapour phase

ybenzene=pbenzenePtotal=3545=79=0.777…y_{\text{benzene}}=\frac{p_{\text{benzene}}}{P_{\text{total}}}=\frac{35}{45}=\frac{7}{9}=0.777\ldotsybenzene​=Ptotal​pbenzene​​=4535​=97​=0.777…

  1. Convert into the required form

Question asks for: ‾×10−2\underline{\hspace{2cm}}\times 10^{-2}​×10−2

Now, 0.777…=77.7…×10−20.777\ldots = 77.7\ldots \times 10^{-2}0.777…=77.7…×10−2

Nearest integer =78=78=78.

Therefore, the required answer is: 78\boxed{78}78​

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