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At 20 C, the vapour pressure of benzene is 70 torr and that of methyl benzene is 20 torr. The mole fraction of benzene in the vapour phase at 20 above an equimolar mixture of benzene and methyl benzene is 10 2. (Nearest integer)
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Correct answer: 78
- Use Raoult’s law for an ideal equimolar solution
For an equimolar mixture,
Given vapour pressures at C:
- Benzene:
- Methyl benzene (toluene):
So partial pressures are:
- Find total vapour pressure
- Find mole fraction of benzene in vapour phase
- Convert into the required form
Question asks for:
Now,
Nearest integer .
Therefore, the required answer is:
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