JEE MainChemistrySolutionsNumerical+4 / −1
1 molal aqueous solution of an electrolyte is 60% ionised. The boiling point of the solution at 1 atm is K. (Rounded off to the nearest integer) [Given Kb for () = 0.52 K kg mol 1]
Numerical answer
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Correct answer: 375
- Use elevation in boiling point formula
For a solution, where:
- = van’t Hoff factor
- molal
- Find van’t Hoff factor
Electrolyte:
On complete ionisation: So total ions formed .
Given degree of ionisation:
For an electrolyte giving ions,
Here , so
- Calculate elevation in boiling point
- Find boiling point of solution
Normal boiling point of water at 1 atm is
Hence,
Rounded to nearest integer:
- Comparison with stored answer
Stored correct answer =
Our derived answer matches the stored answer.
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