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Solutions question

2020 · 9 Jan · Shift 1 · Q10
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Solutions question

2020 · 9 Jan · Shift 1 · Q10

JEE MainChemistrySolutionsNumerical+4 / −1
How much amount of NaCl should be added to 600 g of water (ρ\rhoρ = 1.00 g/mL) to decrease the freezing point of water to – 0.2 °C ? ‾\underline{\hspace{2cm}}​. (The freezing point depression constant for water = 2K kg mol–1)
Numerical answer
View written solutionFree

Correct answer: 1.74TO1.76

  1. Use freezing point depression formula

    ΔTf=iKfm\Delta T_f = i K_f mΔTf​=iKf​m

    where:

    • ΔTf=0.2 ∘C\Delta T_f = 0.2\,^\circ\mathrm{C}ΔTf​=0.2∘C
    • Kf=2 K kg mol−1K_f = 2\,\mathrm{K\,kg\,mol^{-1}}Kf​=2Kkgmol−1
    • for NaCl\mathrm{NaCl}NaCl, assuming complete dissociation: i=2i = 2i=2
  2. Calculate molality required

    m=ΔTfiKf=0.22×2=0.05 mol kg−1m = \frac{\Delta T_f}{iK_f} = \frac{0.2}{2\times 2} = 0.05\,\mathrm{mol\,kg^{-1}}m=iKf​ΔTf​​=2×20.2​=0.05molkg−1

  3. Mass of solvent

    Given water = 600 g=0.6 kg600\,\mathrm{g} = 0.6\,\mathrm{kg}600g=0.6kg

  4. Moles of NaCl needed

    n=m×kg of solvent=0.05×0.6=0.03 moln = m \times \text{kg of solvent} = 0.05 \times 0.6 = 0.03\,\mathrm{mol}n=m×kg of solvent=0.05×0.6=0.03mol

  5. Convert moles to mass

    Molar mass of NaCl: M=23+35.5=58.5 g mol−1M = 23 + 35.5 = 58.5\,\mathrm{g\,mol^{-1}}M=23+35.5=58.5gmol−1

    Therefore, w=nM=0.03×58.5=1.755 gw = nM = 0.03 \times 58.5 = 1.755\,\mathrm{g}w=nM=0.03×58.5=1.755g

  6. Final answer

    Required amount of NaCl: 1.76 g\boxed{1.76\,\mathrm{g}}1.76g​

  7. Comparison with stored correct answer

    Stored correct answer: 1.741.741.74 to 1.761.761.76

    Our answer 1.755 g1.755\,\mathrm{g}1.755g lies in this range, so it agrees.

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