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Solutions question

2016 · 10 Apr · Shift 1 · Q12
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Solutions question

2016 · 10 Apr · Shift 1 · Q12

JEE MainChemistrySolutionsMCQ+4 / −1
An aqueous solution of a salt MX2MX_2MX2​ at certain temperature has a van’t Hoff factor of 2. The degree of dissociation for this solution of the salt is :
  1. A
    0.33
  2. B
    0.50
  3. C
    0.67
  4. D
    0.80
View written solutionFree

Correct answer: B

  1. Write the dissociation of the salt

For the salt MX2MX_2MX2​ in aqueous solution:

MX2→M2++2X−MX_2 \rightarrow M^{2+} + 2X^-MX2​→M2++2X−

So, on complete dissociation, 1 formula unit gives 3 particles.

  1. Use the van’t Hoff factor formula

If the degree of dissociation is α\alphaα, then for a solute that gives ν\nuν particles on dissociation,

i=1+(ν−1)αi = 1 + (\nu - 1)\alphai=1+(ν−1)α

Here, ν=3\nu = 3ν=3, so

i=1+(3−1)α=1+2αi = 1 + (3-1)\alpha = 1 + 2\alphai=1+(3−1)α=1+2α

  1. Substitute the given value of iii

Given van’t Hoff factor:

i=2i = 2i=2

Thus,

2=1+2α2 = 1 + 2\alpha2=1+2α

2α=12\alpha = 12α=1

α=0.50\alpha = 0.50α=0.50

  1. Match with the options

α=0.50\alpha = 0.50α=0.50

So the correct option is B.

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