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Practical Organic Chemistry question

2022 · 27 Jul · Shift 2 · Q21
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Practical Organic Chemistry question

2022 · 27 Jul · Shift 2 · Q21

JEE MainChemistryPractical Organic ChemistryNumerical+4 / −1
JEE Main 2022 (Online) 27th July Evening Shift Chemistry - Practical Organic Chemistry Question 40 English In the above reaction, 5 g5 \mathrm{~g}5 g of toluene is converted into benzaldehyde with 92%92 \%92% yield. The amount of benzaldehyde produced is ‾\underline{\hspace{2cm}}​×10−2 g\times 10^{-2} \mathrm{~g}×10−2 g. (Nearest integer)
Numerical answer
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Correct answer: 530

  1. Identify the reaction and stoichiometry

    Toluene is converted to benzaldehyde: C6H5CH3→C6H5CHO\mathrm{C_6H_5CH_3 \rightarrow C_6H_5CHO}C6​H5​CH3​→C6​H5​CHO

    This is a 1 : 1 molar conversion.

  2. Calculate molar masses

    • Toluene, C7H8\mathrm{C_7H_8}C7​H8​: 7×12+8×1=84+8=92 g mol−17 \times 12 + 8 \times 1 = 84 + 8 = 92\,\text{g mol}^{-1}7×12+8×1=84+8=92g mol−1

    • Benzaldehyde, C7H6O\mathrm{C_7H_6O}C7​H6​O: 7×12+6×1+16=84+6+16=106 g mol−17 \times 12 + 6 \times 1 + 16 = 84 + 6 + 16 = 106\,\text{g mol}^{-1}7×12+6×1+16=84+6+16=106g mol−1

  3. Find moles of toluene used

    Given mass of toluene = 5 g5\,\text{g}5g ntoluene=592 moln_{\text{toluene}} = \frac{5}{92}\,\text{mol}ntoluene​=925​mol

  4. Theoretical mass of benzaldehyde

    Since mole ratio is 1:11:11:1, nbenzaldehyde=592 moln_{\text{benzaldehyde}} = \frac{5}{92}\,\text{mol}nbenzaldehyde​=925​mol

    So theoretical mass of benzaldehyde is mtheoretical=592×106m_{\text{theoretical}} = \frac{5}{92} \times 106mtheoretical​=925​×106 =5.7609 g= 5.7609\,\text{g}=5.7609g

  5. Apply 92% yield

    mactual=5.7609×92100m_{\text{actual}} = 5.7609 \times \frac{92}{100}mactual​=5.7609×10092​ =5.3000 g= 5.3000\,\text{g}=5.3000g

  6. Express in the required form

    We need: ‾×10−2 g\underline{\hspace{2cm}} \times 10^{-2}\,\text{g}​×10−2g

    Since 5.3000 g=530×10−2 g5.3000\,\text{g} = 530 \times 10^{-2}\,\text{g}5.3000g=530×10−2g

    Hence, the required integer is: 530\boxed{530}530​

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