JEE MainChemistryPractical Organic ChemistryNumerical+4 / −1
A 2.0 g sample containing is treated with liberating . The gas is passed into a solution of and 60.0 mL of 0.1 M is required to titrate the liberated iodine. The percentage of in the sample is . (Nearest integer) [Atomic masses (in u) Mn = 55; Cl = 35.5; O = 16, I = 127, Na = 23, K = 39, S = 32]
Numerical answer
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Correct answer: 13
- Reactions involved
When reacts with hydrochloric acid:
Thus, mole of liberates mole of .
The liberated chlorine reacts with potassium iodide:
Thus, mole of liberates mole of .
The iodine is titrated with sodium thiosulfate:
Thus, mole of requires moles of .
- Moles of used
Volume of solution
Molarity
- Moles of liberated
From
so,
- Moles of produced
Since
- Moles of in sample
Since
- Mass of
Molar mass of :
Therefore,
- Percentage of in 2.0 g sample
Nearest integer:
- Comparison with stored answer
Stored correct answer =
Our derived answer =
So, the answer agrees with the stored correct answer.
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