- AStatement I is correct but Statement II is incorrect
- BBoth Statement I and Statement II are correct
- CStatement I is incorrect but Statement II is correct
- DBoth Statement I and Statement II are incorrect
View written solutionFree
Correct answer: C
-
Check Statement (I): Metallic radius of Al vs Ga
Normally, on moving down a group, atomic/metallic radius should increase. So one may expect:
However, in group 13, gallium comes after the filling of orbitals. The electrons shield poorly, causing greater effective nuclear charge on the outer electrons of Ga. This is known as d-block contraction.
As a result, Ga has an unexpectedly small atomic/metallic radius, and in fact:
Therefore, the statement
"The metallic radius of Al is less than that of Ga" is incorrect.
-
Check Statement (II): Ionic radius of vs
For the ions and , gallium again experiences the effect of poor shielding by -electrons before ion formation. Standard ionic radii show:
Hence,
So Statement (II) is correct.
-
Conclusion
- Statement (I): Incorrect
- Statement (II): Correct
Therefore, the correct option is:
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