- AA, B, C and D
- BA and C only
- CB only
- DB and D only
View written solutionFree
Correct answer: C
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Elements considered
The first four elements of group 17 are:
We check which properties show irregularity in their trend.
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(A) Covalent radius
Down the group, atomic size increases because a new shell is added each time.
Hence covalent radius follows:
This is a regular increase. So no irregularity.
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(B) Electron affinity
In general, electron affinity becomes less negative down a group, but fluorine is an exception.
Expected trend would suggest fluorine should have the most negative electron affinity, but actually: in magnitude of electron affinity.
This happens because the added electron in fluorine enters the very compact orbital, where electron-electron repulsion is high.
So electron affinity shows an irregularity.
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(C) Ionic radius
For halide ions:
Ionic radius increases regularly down the group due to increase in number of shells.
So no irregularity.
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(D) First ionization energy
Down the group, first ionization energy decreases regularly because atomic size increases and shielding increases.
Thus:
This is a regular trend, not irregular.
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Conclusion
Only electron affinity shows irregularity among the first four elements of group 17.
Therefore the correct choice is:
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Match with given options
Option C corresponds to B only.
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Comparison with stored answer
Stored correct answer = C
Our derived answer = C
So they agree.
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